Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin

Two Schiff base compounds namely 4,4'-(1E,1'Z)-(hexane-1,6-diylbis(azan-1-yl-1-ylidene)) bis(methan-1-yl-1-ylidene)diphenol as SB1 and 2-(4-hydroxybenzylidene amino)-2-(hydroxymethyl)butane-1,4-diol as SB2 were derived from appropriate amine and aldehydes have been synthesized in ratio of...

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Main Author: Hafidzuddin, Mohd Emir Hafidz
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2010
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/23167/
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author Hafidzuddin, Mohd Emir Hafidz
author_facet Hafidzuddin, Mohd Emir Hafidz
author_sort Hafidzuddin, Mohd Emir Hafidz
building UiTM Institutional Repository
collection Online Access
description Two Schiff base compounds namely 4,4'-(1E,1'Z)-(hexane-1,6-diylbis(azan-1-yl-1-ylidene)) bis(methan-1-yl-1-ylidene)diphenol as SB1 and 2-(4-hydroxybenzylidene amino)-2-(hydroxymethyl)butane-1,4-diol as SB2 were derived from appropriate amine and aldehydes have been synthesized in ratio of 1:2 in ethanolic solution. The structures of the Schiff bases are investigated using ¹H NMR spectroscopy and FTIR spectroscopy. Results obtained from all characterization methods are closely matched with the theoretical values. It can be suggested that the required products of SB1 and SB2 have been successfully synthesized. Inhibition effect of two Schiff bases SB1 and SB2 as corrosion inhibitors on carbon steel in 1.0 M HCl solution has been studied using weight loss method. The result of investigation showed that all two compound act as good corrosion inhibitor. Inhibition efficiency increased with increasing concentration of inhibitors with SB2 exhibited the highest inhibition efficiency at 51.61% in concentration 3 x 10⁻⁵ M. Substituent of methyl and hydroxyl group on the benzene ring increases the inhibition efficiency. The decreasing efficiency of Schiff bases in the study could be noted as SB2 > SB1 accordingly at higher concentration.
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spelling uitm-231672019-02-14T04:49:57Z https://ir.uitm.edu.my/id/eprint/23167/ Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin Hafidzuddin, Mohd Emir Hafidz Materials of engineering and construction Two Schiff base compounds namely 4,4'-(1E,1'Z)-(hexane-1,6-diylbis(azan-1-yl-1-ylidene)) bis(methan-1-yl-1-ylidene)diphenol as SB1 and 2-(4-hydroxybenzylidene amino)-2-(hydroxymethyl)butane-1,4-diol as SB2 were derived from appropriate amine and aldehydes have been synthesized in ratio of 1:2 in ethanolic solution. The structures of the Schiff bases are investigated using ¹H NMR spectroscopy and FTIR spectroscopy. Results obtained from all characterization methods are closely matched with the theoretical values. It can be suggested that the required products of SB1 and SB2 have been successfully synthesized. Inhibition effect of two Schiff bases SB1 and SB2 as corrosion inhibitors on carbon steel in 1.0 M HCl solution has been studied using weight loss method. The result of investigation showed that all two compound act as good corrosion inhibitor. Inhibition efficiency increased with increasing concentration of inhibitors with SB2 exhibited the highest inhibition efficiency at 51.61% in concentration 3 x 10⁻⁵ M. Substituent of methyl and hydroxyl group on the benzene ring increases the inhibition efficiency. The decreasing efficiency of Schiff bases in the study could be noted as SB2 > SB1 accordingly at higher concentration. Faculty of Applied Sciences 2010 Student Project NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/23167/1/PPb_MOHD%20EMIR%20HAFIDZ%20HAFIDZUDDIN%20AS%2010_5.pdf Hafidzuddin, Mohd Emir Hafidz (2010) Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin. (2010) [Student Project] <http://terminalib.uitm.edu.my/23167.pdf> (Unpublished)
spellingShingle Materials of engineering and construction
Hafidzuddin, Mohd Emir Hafidz
Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin
title Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin
title_full Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin
title_fullStr Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin
title_full_unstemmed Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin
title_short Corrosion inhibition of carbon steel using schiff base ligands in 1.0 M hydrochloric solution / Mohd Emir Hafidz Hafidzuddin
title_sort corrosion inhibition of carbon steel using schiff base ligands in 1.0 m hydrochloric solution / mohd emir hafidz hafidzuddin
topic Materials of engineering and construction
url https://ir.uitm.edu.my/id/eprint/23167/