Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan

In this study, MCM-41 was synthesized by using cetyltrimethylammonium bromide (CTAB) as structure directing surfactant, functionalized with trimethylchlorosilane and used as adsorbent for the toxic metal ions i.e. arsenic (V) in aqueous solution. The synthesized and functionalized MCM-41 was charact...

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Main Author: Roslan, Nurul Asnyirah
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2010
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/23111/
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author Roslan, Nurul Asnyirah
author_facet Roslan, Nurul Asnyirah
author_sort Roslan, Nurul Asnyirah
building UiTM Institutional Repository
collection Online Access
description In this study, MCM-41 was synthesized by using cetyltrimethylammonium bromide (CTAB) as structure directing surfactant, functionalized with trimethylchlorosilane and used as adsorbent for the toxic metal ions i.e. arsenic (V) in aqueous solution. The synthesized and functionalized MCM-41 was characterized using Fourier Transform Infra Red (FTIR). The Induced Coupled- Plasma (ICP-OES) was applied in optimization study for detection of arsenic (V) in aqueous solution which including effect of pH, effect of contact time at different initial concentration, effect of adsorbent dosage and effect of temperature. Results demonstrate that organosilane functionalized MCM-41 has low adsorption capacity for arsenic since it can only remove less than 50 % of arsenic in aqueous solution. The highest amount of arsenic adsorbed was 50.56 % in 50 mg/L of arsenic concentration after 2 hours of the test in pH 7 under stirring condition.
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spelling uitm-231112019-02-27T04:51:09Z https://ir.uitm.edu.my/id/eprint/23111/ Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan Roslan, Nurul Asnyirah Salts Analytical chemistry In this study, MCM-41 was synthesized by using cetyltrimethylammonium bromide (CTAB) as structure directing surfactant, functionalized with trimethylchlorosilane and used as adsorbent for the toxic metal ions i.e. arsenic (V) in aqueous solution. The synthesized and functionalized MCM-41 was characterized using Fourier Transform Infra Red (FTIR). The Induced Coupled- Plasma (ICP-OES) was applied in optimization study for detection of arsenic (V) in aqueous solution which including effect of pH, effect of contact time at different initial concentration, effect of adsorbent dosage and effect of temperature. Results demonstrate that organosilane functionalized MCM-41 has low adsorption capacity for arsenic since it can only remove less than 50 % of arsenic in aqueous solution. The highest amount of arsenic adsorbed was 50.56 % in 50 mg/L of arsenic concentration after 2 hours of the test in pH 7 under stirring condition. Faculty of Applied Sciences 2010 Student Project NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/23111/1/PPb_NURUL%20ASNYIRAH%20ROSLAN%20AS%2010_5.pdf Roslan, Nurul Asnyirah (2010) Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan. (2010) [Student Project] <http://terminalib.uitm.edu.my/23111.pdf> (Unpublished)
spellingShingle Salts
Analytical chemistry
Roslan, Nurul Asnyirah
Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan
title Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan
title_full Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan
title_fullStr Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan
title_full_unstemmed Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan
title_short Removal of arsenic (V) from aqueous solution by using silylated MCM-41 / Nurul Asnyirah Roslan
title_sort removal of arsenic (v) from aqueous solution by using silylated mcm-41 / nurul asnyirah roslan
topic Salts
Analytical chemistry
url https://ir.uitm.edu.my/id/eprint/23111/