Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan
Two Schiff base ligand has been synthesized by the condensation of salicylaldehyde with aniline and 1,2-diaminocyclohexane which produced p-benzalaminophenol [SBl] and N,N'-bis(salicylidene)cyclohexanediamine [SB2] respectively. The ligands were further synthesized with manganese (II) acetate w...
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| Format: | Student Project |
| Language: | English |
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Faculty of Applied Sciences
2010
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| Online Access: | https://ir.uitm.edu.my/id/eprint/23095/ |
| _version_ | 1848805660104327168 |
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| author | Roslan, Norhafiza |
| author_facet | Roslan, Norhafiza |
| author_sort | Roslan, Norhafiza |
| building | UiTM Institutional Repository |
| collection | Online Access |
| description | Two Schiff base ligand has been synthesized by the condensation of salicylaldehyde with aniline and 1,2-diaminocyclohexane which produced p-benzalaminophenol [SBl] and N,N'-bis(salicylidene)cyclohexanediamine [SB2] respectively. The ligands were further synthesized with manganese (II) acetate which produced [Mn(II){SBl}] and [Mn(II){SB2}] complexes. These ligands and complexes were then characterized by elemental CHN analysis, FTIR, UV-Vis, ¹H-NMR and ¹³C-NMR spectroscopies. FTIR, UV-Vis, ¹H-NMR and ¹³C-NMR spectroscopic data revealed that the ligands acted as bidentate ligand for [SBl] and tetradentate ligand for [SB2]. While FTIR and UV-Vis spectroscopic data showed that the ligands from [SBl] and [SB2] were coordinated to Mn atom through both the azomethine N atoms and phenolic O atoms to become as their complexes. |
| first_indexed | 2025-11-14T22:14:34Z |
| format | Student Project |
| id | uitm-23095 |
| institution | Universiti Teknologi MARA |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T22:14:34Z |
| publishDate | 2010 |
| publisher | Faculty of Applied Sciences |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | uitm-230952019-02-27T07:53:57Z https://ir.uitm.edu.my/id/eprint/23095/ Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan Roslan, Norhafiza Schiff bases Two Schiff base ligand has been synthesized by the condensation of salicylaldehyde with aniline and 1,2-diaminocyclohexane which produced p-benzalaminophenol [SBl] and N,N'-bis(salicylidene)cyclohexanediamine [SB2] respectively. The ligands were further synthesized with manganese (II) acetate which produced [Mn(II){SBl}] and [Mn(II){SB2}] complexes. These ligands and complexes were then characterized by elemental CHN analysis, FTIR, UV-Vis, ¹H-NMR and ¹³C-NMR spectroscopies. FTIR, UV-Vis, ¹H-NMR and ¹³C-NMR spectroscopic data revealed that the ligands acted as bidentate ligand for [SBl] and tetradentate ligand for [SB2]. While FTIR and UV-Vis spectroscopic data showed that the ligands from [SBl] and [SB2] were coordinated to Mn atom through both the azomethine N atoms and phenolic O atoms to become as their complexes. Faculty of Applied Sciences 2010 Student Project NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/23095/1/PPb_NORHAFIZA%20ROSLAN%20AS%2010_5.pdf Roslan, Norhafiza (2010) Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan. (2010) [Student Project] <http://terminalib.uitm.edu.my/23095.pdf> (Unpublished) |
| spellingShingle | Schiff bases Roslan, Norhafiza Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan |
| title | Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan |
| title_full | Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan |
| title_fullStr | Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan |
| title_full_unstemmed | Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan |
| title_short | Synthesis and characterization of manganese (II) complexes with N, O- donor schiff base / Norhafiza Roslan |
| title_sort | synthesis and characterization of manganese (ii) complexes with n, o- donor schiff base / norhafiza roslan |
| topic | Schiff bases |
| url | https://ir.uitm.edu.my/id/eprint/23095/ |