Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.]

In this study, Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) was prepared by acetic acid-assisted sol-gel method The structural properties of NASICON phosphates material with chemical formula LiTi₂(P0₄)₃ were observed using the Fourier transform infrared spectroscopy. NASICON is a family of crystallin...

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Main Authors: Hamidi, Maziidah, Mohamed, S. N., Raja Mustapha, Raja Ibrahim Puter, Hassan, Oskar Hasdinor, Yahya, Muhd Zu Azhan
Format: Article
Language:English
Published: Institute of Research Management and Innovation (IRMI) 2015
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/16083/
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author Hamidi, Maziidah
Mohamed, S. N.
Raja Mustapha, Raja Ibrahim Puter
Hassan, Oskar Hasdinor
Yahya, Muhd Zu Azhan
author_facet Hamidi, Maziidah
Mohamed, S. N.
Raja Mustapha, Raja Ibrahim Puter
Hassan, Oskar Hasdinor
Yahya, Muhd Zu Azhan
author_sort Hamidi, Maziidah
building UiTM Institutional Repository
collection Online Access
description In this study, Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) was prepared by acetic acid-assisted sol-gel method The structural properties of NASICON phosphates material with chemical formula LiTi₂(P0₄)₃ were observed using the Fourier transform infrared spectroscopy. NASICON is a family of crystalline phosphate with a general network system consisting of P0₄ tetrahedra, thus bands were assigned by vibrations contributed by basic phosphates, in the wavenumber region between 1300 cm1 and 600 cm1. Experimental spectra indicated that all Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5), heat treated at 600°C and 700°Cfor 3 hours in air, samples showed the presence of phosphate peaks with shift in frequency asAl3⁺ is substituted into the structure, and with increasing temperatures. Some bands broadened and overlapped causing it hard to analyze the arising bands. It however determined the existence of NASICON structure in all of the samples under study.
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spelling uitm-160832017-02-02T07:44:29Z https://ir.uitm.edu.my/id/eprint/16083/ Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.] srj Hamidi, Maziidah Mohamed, S. N. Raja Mustapha, Raja Ibrahim Puter Hassan, Oskar Hasdinor Yahya, Muhd Zu Azhan Physical and theoretical chemistry In this study, Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) was prepared by acetic acid-assisted sol-gel method The structural properties of NASICON phosphates material with chemical formula LiTi₂(P0₄)₃ were observed using the Fourier transform infrared spectroscopy. NASICON is a family of crystalline phosphate with a general network system consisting of P0₄ tetrahedra, thus bands were assigned by vibrations contributed by basic phosphates, in the wavenumber region between 1300 cm1 and 600 cm1. Experimental spectra indicated that all Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5), heat treated at 600°C and 700°Cfor 3 hours in air, samples showed the presence of phosphate peaks with shift in frequency asAl3⁺ is substituted into the structure, and with increasing temperatures. Some bands broadened and overlapped causing it hard to analyze the arising bands. It however determined the existence of NASICON structure in all of the samples under study. Institute of Research Management and Innovation (IRMI) 2015 Article PeerReviewed text en https://ir.uitm.edu.my/id/eprint/16083/1/AJ_MAZIIDAH%20HAMIDI%20SRJ%2015.pdf Hamidi, Maziidah and Mohamed, S. N. and Raja Mustapha, Raja Ibrahim Puter and Hassan, Oskar Hasdinor and Yahya, Muhd Zu Azhan (2015) Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.]. (2015) Scientific Research Journal <https://ir.uitm.edu.my/view/publication/Scientific_Research_Journal.html>, 12 (2). pp. 36-44. ISSN 1675-7009 https://srj.uitm.edu.my/
spellingShingle Physical and theoretical chemistry
Hamidi, Maziidah
Mohamed, S. N.
Raja Mustapha, Raja Ibrahim Puter
Hassan, Oskar Hasdinor
Yahya, Muhd Zu Azhan
Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.]
title Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.]
title_full Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.]
title_fullStr Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.]
title_full_unstemmed Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.]
title_short Vibrational analysis of Li₁₊ₓAlₓTi₂₋ₓ(P0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / Maziidah Hamidi … [et al.]
title_sort vibrational analysis of li₁₊ₓalₓti₂₋ₓ(p0₄)₃ (0.0 < x < 0.5) glass ceramic electrolytes prepared by acetic acid-assisted sol-gel method / maziidah hamidi … [et al.]
topic Physical and theoretical chemistry
url https://ir.uitm.edu.my/id/eprint/16083/
https://ir.uitm.edu.my/id/eprint/16083/