[O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I)
The synthesis, spectroscopic characterization and X-ray crystal structure of the title compound, (4-tolyl)3PAu[SC(O-i-Pr)=NC6H4NO2-4] (1) are described. Spectroscopy exhibited the expected features confirming the formation of the compound. The molecular structure of 1 confirms the expected linear P–...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI
2018
|
| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/933/ http://eprints.sunway.edu.my/933/1/Tiekink%20Molbank-2018.pdf |
| _version_ | 1848801931543183360 |
|---|---|
| author | Yeo, Chien Ing * Tiekink, Edward R. T. * |
| author_facet | Yeo, Chien Ing * Tiekink, Edward R. T. * |
| author_sort | Yeo, Chien Ing * |
| building | SU Institutional Repository |
| collection | Online Access |
| description | The synthesis, spectroscopic characterization and X-ray crystal structure of the title compound, (4-tolyl)3PAu[SC(O-i-Pr)=NC6H4NO2-4] (1) are described. Spectroscopy exhibited the expected features confirming the formation of the compound. The molecular structure of 1 confirms the expected linear P–Au–S coordination geometry defined by thiolate-S and phosphane-P atoms. The nearly 7◦ deviation from linearity is ascribed to the close approach of the imine-bound phenyl group, indicative of a semi-localized Au . . . π(arene) interaction. The three-dimensional molecular
packing is consolidated by methyl- and tolyl-C–H . . . O(nitro) and tolyl-C–H . . . π(tolyl) interactions. |
| first_indexed | 2025-11-14T21:15:18Z |
| format | Article |
| id | sunway-933 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:15:18Z |
| publishDate | 2018 |
| publisher | MDPI |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-9332020-10-12T07:49:29Z http://eprints.sunway.edu.my/933/ [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I) Yeo, Chien Ing * Tiekink, Edward R. T. * QD Chemistry The synthesis, spectroscopic characterization and X-ray crystal structure of the title compound, (4-tolyl)3PAu[SC(O-i-Pr)=NC6H4NO2-4] (1) are described. Spectroscopy exhibited the expected features confirming the formation of the compound. The molecular structure of 1 confirms the expected linear P–Au–S coordination geometry defined by thiolate-S and phosphane-P atoms. The nearly 7◦ deviation from linearity is ascribed to the close approach of the imine-bound phenyl group, indicative of a semi-localized Au . . . π(arene) interaction. The three-dimensional molecular packing is consolidated by methyl- and tolyl-C–H . . . O(nitro) and tolyl-C–H . . . π(tolyl) interactions. MDPI 2018 Article PeerReviewed text en http://eprints.sunway.edu.my/933/1/Tiekink%20Molbank-2018.pdf Yeo, Chien Ing * and Tiekink, Edward R. T. * (2018) [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I). Molbank, 2018 (4). M1028. ISSN 1422-8599 http://doi.org/10.3390/M1028 doi:10.3390/M1028 |
| spellingShingle | QD Chemistry Yeo, Chien Ing * Tiekink, Edward R. T. * [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I) |
| title | [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I) |
| title_full | [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I) |
| title_fullStr | [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I) |
| title_full_unstemmed | [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I) |
| title_short | [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I) |
| title_sort | [o-isopropyl-n-(4-nitrophenyl)thiocarbamato-κs]-(tri-4-tolylphosphine-κp)gold(i) |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/933/ http://eprints.sunway.edu.my/933/ http://eprints.sunway.edu.my/933/ http://eprints.sunway.edu.my/933/1/Tiekink%20Molbank-2018.pdf |