O-Methyl m-Tolylcarbamothioate
The synthesis, spectroscopic, and crystallographic characterisation of the title compound,O-methyl m-tolylcarbamothioate, MeOC(=S)N(H)(m-tolyl) (1), are described. The crystallographic study confirms the structure determined by spectroscopy and shows the presence of the thioamide tautomer, a syn-di...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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MDPi
2018
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| Online Access: | http://eprints.sunway.edu.my/902/ http://eprints.sunway.edu.my/902/1/Tiekink%20O%20Methyl%20m%20Tolycarbamothioate.pdf |
| _version_ | 1848801925046206464 |
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| author | Yeo, Chien Ing * Tiekink, Edward R. T. * |
| author_facet | Yeo, Chien Ing * Tiekink, Edward R. T. * |
| author_sort | Yeo, Chien Ing * |
| building | SU Institutional Repository |
| collection | Online Access |
| description | The synthesis, spectroscopic, and crystallographic characterisation of the title compound,O-methyl m-tolylcarbamothioate, MeOC(=S)N(H)(m-tolyl) (1), are described. The crystallographic study confirms the structure determined by spectroscopy and shows the presence of the thioamide
tautomer, a syn-disposition of the thione-S and thioamide-N-H atoms and, in the crystal, thioamide-N-H . . . S(thione) hydrogen bonding leading to an eight-membered { . . . HNCS}2 synthon. |
| first_indexed | 2025-11-14T21:15:11Z |
| format | Article |
| id | sunway-902 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:15:11Z |
| publishDate | 2018 |
| publisher | MDPi |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-9022020-10-12T07:46:19Z http://eprints.sunway.edu.my/902/ O-Methyl m-Tolylcarbamothioate Yeo, Chien Ing * Tiekink, Edward R. T. * QD Chemistry The synthesis, spectroscopic, and crystallographic characterisation of the title compound,O-methyl m-tolylcarbamothioate, MeOC(=S)N(H)(m-tolyl) (1), are described. The crystallographic study confirms the structure determined by spectroscopy and shows the presence of the thioamide tautomer, a syn-disposition of the thione-S and thioamide-N-H atoms and, in the crystal, thioamide-N-H . . . S(thione) hydrogen bonding leading to an eight-membered { . . . HNCS}2 synthon. MDPi 2018-09-15 Article PeerReviewed text en http://eprints.sunway.edu.my/902/1/Tiekink%20O%20Methyl%20m%20Tolycarbamothioate.pdf Yeo, Chien Ing * and Tiekink, Edward R. T. * (2018) O-Methyl m-Tolylcarbamothioate. Molbank, 2018 (3). M1020. ISSN 1422-8599 http://doi.org/10.3390/M1020 doi:10.3390/M1020 |
| spellingShingle | QD Chemistry Yeo, Chien Ing * Tiekink, Edward R. T. * O-Methyl m-Tolylcarbamothioate |
| title | O-Methyl m-Tolylcarbamothioate |
| title_full | O-Methyl m-Tolylcarbamothioate |
| title_fullStr | O-Methyl m-Tolylcarbamothioate |
| title_full_unstemmed | O-Methyl m-Tolylcarbamothioate |
| title_short | O-Methyl m-Tolylcarbamothioate |
| title_sort | o-methyl m-tolylcarbamothioate |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/902/ http://eprints.sunway.edu.my/902/ http://eprints.sunway.edu.my/902/ http://eprints.sunway.edu.my/902/1/Tiekink%20O%20Methyl%20m%20Tolycarbamothioate.pdf |