O-Methyl m-Tolylcarbamothioate
The synthesis, spectroscopic, and crystallographic characterisation of the title compound,O-methyl m-tolylcarbamothioate, MeOC(=S)N(H)(m-tolyl) (1), are described. The crystallographic study confirms the structure determined by spectroscopy and shows the presence of the thioamide tautomer, a syn-di...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPi
2018
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| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/902/ http://eprints.sunway.edu.my/902/1/Tiekink%20O%20Methyl%20m%20Tolycarbamothioate.pdf |
| Summary: | The synthesis, spectroscopic, and crystallographic characterisation of the title compound,O-methyl m-tolylcarbamothioate, MeOC(=S)N(H)(m-tolyl) (1), are described. The crystallographic study confirms the structure determined by spectroscopy and shows the presence of the thioamide
tautomer, a syn-disposition of the thione-S and thioamide-N-H atoms and, in the crystal, thioamide-N-H . . . S(thione) hydrogen bonding leading to an eight-membered { . . . HNCS}2 synthon. |
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