Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates
This bibliographic review summarises the coordination chemistry of mono- and diselenium analogues of metal dithiocarbamate ligands, [RRꞌNCS2]-, as revealed by X-ray crystallography and spectroscopy (77Se NMR and infrared). The Se-ligands are usually chelating but, bridging modes, up to 4, are know...
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| Format: | Article |
| Language: | English |
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Elsevier
2018
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| Online Access: | http://eprints.sunway.edu.my/898/ http://eprints.sunway.edu.my/898/1/Tiekink%20Molecular%20and%20supramolecular.pdf |
| _version_ | 1848801923810983936 |
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| author | Lee, See Mun * Heard, Peter * Tiekink, Edward R. T. * |
| author_facet | Lee, See Mun * Heard, Peter * Tiekink, Edward R. T. * |
| author_sort | Lee, See Mun * |
| building | SU Institutional Repository |
| collection | Online Access |
| description | This bibliographic review summarises the coordination chemistry of mono- and diselenium analogues of metal dithiocarbamate ligands, [RRꞌNCS2]-, as revealed by X-ray
crystallography and spectroscopy (77Se NMR and infrared). The Se-ligands are usually chelating but, bridging modes, up to 4, are known. Reflecting the larger size, greater
polarisability and presence of a polar-cap (-hole), selenium atoms are more likely to be involved in secondary-bonding (chalcogen-bonding) than sulphur when a competition exists. Isostructural relationships are established across the series in about one-third of the structures. |
| first_indexed | 2025-11-14T21:15:10Z |
| format | Article |
| id | sunway-898 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:15:10Z |
| publishDate | 2018 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-8982021-04-16T03:56:24Z http://eprints.sunway.edu.my/898/ Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates Lee, See Mun * Heard, Peter * Tiekink, Edward R. T. * QD Chemistry This bibliographic review summarises the coordination chemistry of mono- and diselenium analogues of metal dithiocarbamate ligands, [RRꞌNCS2]-, as revealed by X-ray crystallography and spectroscopy (77Se NMR and infrared). The Se-ligands are usually chelating but, bridging modes, up to 4, are known. Reflecting the larger size, greater polarisability and presence of a polar-cap (-hole), selenium atoms are more likely to be involved in secondary-bonding (chalcogen-bonding) than sulphur when a competition exists. Isostructural relationships are established across the series in about one-third of the structures. Elsevier 2018-11-15 Article PeerReviewed text en cc_by_4 http://eprints.sunway.edu.my/898/1/Tiekink%20Molecular%20and%20supramolecular.pdf Lee, See Mun * and Heard, Peter * and Tiekink, Edward R. T. * (2018) Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates. Coordination Chemistry Reviews, 375. pp. 410-423. ISSN 0010-8545 |
| spellingShingle | QD Chemistry Lee, See Mun * Heard, Peter * Tiekink, Edward R. T. * Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates |
| title | Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates |
| title_full | Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates |
| title_fullStr | Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates |
| title_full_unstemmed | Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates |
| title_short | Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates |
| title_sort | molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/898/ http://eprints.sunway.edu.my/898/1/Tiekink%20Molecular%20and%20supramolecular.pdf |