Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis
The title cluster compound, [Ru3(C19H17PS)(CO)11], comprises a triangle of Ru0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand, PPh2(C6H4SMe-4); no Ru� � �S interactions are...
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| Language: | English |
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International Union of Crystallography
2018
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| Online Access: | http://eprints.sunway.edu.my/833/ http://eprints.sunway.edu.my/833/1/Tiekink%20Undecacarbonyl%20Acta%20Cryst.%20%282018%29.%20E74%20791-795.pdf |
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| author | Omar Shawkataly, Hafiz Malik Hussein, Adnelnasir Siti Syaida Sirat, Jotani, Mukesh M. Tiekink, Edward R. T. * |
| author_facet | Omar Shawkataly, Hafiz Malik Hussein, Adnelnasir Siti Syaida Sirat, Jotani, Mukesh M. Tiekink, Edward R. T. * |
| author_sort | Omar Shawkataly, |
| building | SU Institutional Repository |
| collection | Online Access |
| description | The title cluster compound, [Ru3(C19H17PS)(CO)11], comprises a triangle of Ru0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is
bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand, PPh2(C6H4SMe-4); no Ru� � �S interactions are observed. The phosphane occupies an equatorial position and its proximity to an Ru—Ru edge
results in the elongation of this bond with respect to the others [2.8933 (2) A ° cf. 2.8575 (2) and 2.8594 (3) A ° ]. In the crystal, phenyl-C—H...�O(carbonyl) and
carbonyl-O� � �O(carbonyl) [2.817 (2) A ° ] interactions combine to form a supramolecular chain propagating along [111]; the chains pack without directional
interactions between them. The carbonyl-O...�O(carbonyl) and other weak contacts have an influence upon the Hirshfeld surfaces with O...�H contacts making the greatest contribution, i.e. 37.4% cf. 15.8% for O� � �O and 15.6% for
H� � �H contacts. |
| first_indexed | 2025-11-14T21:14:54Z |
| format | Article |
| id | sunway-833 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:14:54Z |
| publishDate | 2018 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-8332020-10-07T09:06:34Z http://eprints.sunway.edu.my/833/ Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis Omar Shawkataly, Hafiz Malik Hussein, Adnelnasir Siti Syaida Sirat, Jotani, Mukesh M. Tiekink, Edward R. T. * QD Chemistry The title cluster compound, [Ru3(C19H17PS)(CO)11], comprises a triangle of Ru0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand, PPh2(C6H4SMe-4); no Ru� � �S interactions are observed. The phosphane occupies an equatorial position and its proximity to an Ru—Ru edge results in the elongation of this bond with respect to the others [2.8933 (2) A ° cf. 2.8575 (2) and 2.8594 (3) A ° ]. In the crystal, phenyl-C—H...�O(carbonyl) and carbonyl-O� � �O(carbonyl) [2.817 (2) A ° ] interactions combine to form a supramolecular chain propagating along [111]; the chains pack without directional interactions between them. The carbonyl-O...�O(carbonyl) and other weak contacts have an influence upon the Hirshfeld surfaces with O...�H contacts making the greatest contribution, i.e. 37.4% cf. 15.8% for O� � �O and 15.6% for H� � �H contacts. International Union of Crystallography 2018-05-08 Article PeerReviewed text en http://eprints.sunway.edu.my/833/1/Tiekink%20Undecacarbonyl%20Acta%20Cryst.%20%282018%29.%20E74%20791-795.pdf Omar Shawkataly, and Hafiz Malik Hussein, Adnelnasir and Siti Syaida Sirat, and Jotani, Mukesh M. and Tiekink, Edward R. T. * (2018) Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E Crystallographic Communications, 74 (6). pp. 791-795. ISSN 2056-9890 http://doi.org/10.1107/S2056989018006989 doi:10.1107/S2056989018006989 |
| spellingShingle | QD Chemistry Omar Shawkataly, Hafiz Malik Hussein, Adnelnasir Siti Syaida Sirat, Jotani, Mukesh M. Tiekink, Edward R. T. * Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis |
| title | Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis |
| title_full | Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis |
| title_fullStr | Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis |
| title_short | Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): Crystal structure and Hirshfeld surface analysis |
| title_sort | undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): crystal structure and hirshfeld surface analysis |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/833/ http://eprints.sunway.edu.my/833/ http://eprints.sunway.edu.my/833/ http://eprints.sunway.edu.my/833/1/Tiekink%20Undecacarbonyl%20Acta%20Cryst.%20%282018%29.%20E74%20791-795.pdf |