Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)

The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C4H9)2(C7H14NO2S2)2], (I), and [Sn(C6H5)3(C5H10NOS2)], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the m...

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Main Authors:	Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M., Tiekink, Edward R. T. *
Format:	Article
Language:	English
Published:	2018
Subjects:	QD Chemistry
Online Access:	http://eprints.sunway.edu.my/753/ http://eprints.sunway.edu.my/753/1/Tiekink%20Crystal%20structures%20and%20Hirshfeld.pdf

_version_	1848801891500163072
author	Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M. Tiekink, Edward R. T. *
author_facet	Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M. Tiekink, Edward R. T. *
author_sort	Mohamad Rapidah,
building	SU Institutional Repository
collection	Online Access
description	The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C4H9)2(C7H14NO2S2)2], (I), and [Sn(C6H5)3(C5H10NOS2)], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the metal atom in (I) and a distorted tetrahedral geometry in (II). The complete molecule of (I) is generated by a crystallographic twofold axis (Sn site symmetry 2). In the crystal of (I), molecules self-assemble into a supramolecular array parallel to (101) via methylene-C—H...O(methoxy) interactions. In the crystal of (II), supramolecular dimers are formed via pairs of weak phenyl-C—H...π(phenyl) contacts. In each of (I) and (II), the speciﬁed assemblies connect into a threedimensional architecture without directional interactions between them. Hirshfeld surface analyses conﬁrm the importance of H...H contacts in the molecular packing of each of (I) and (II), and in the case of (I), highlight the importance of short methoxy-H...H(butyl) contacts between layers.
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format	Article
id	sunway-753
institution	Sunway University
institution_category	Local University
language	English
last_indexed	2025-11-14T21:14:39Z
publishDate	2018
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spelling	sunway-7532020-10-07T09:20:29Z http://eprints.sunway.edu.my/753/ Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV) Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M. Tiekink, Edward R. T. * QD Chemistry The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C4H9)2(C7H14NO2S2)2], (I), and [Sn(C6H5)3(C5H10NOS2)], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the metal atom in (I) and a distorted tetrahedral geometry in (II). The complete molecule of (I) is generated by a crystallographic twofold axis (Sn site symmetry 2). In the crystal of (I), molecules self-assemble into a supramolecular array parallel to (101) via methylene-C—H...O(methoxy) interactions. In the crystal of (II), supramolecular dimers are formed via pairs of weak phenyl-C—H...π(phenyl) contacts. In each of (I) and (II), the speciﬁed assemblies connect into a threedimensional architecture without directional interactions between them. Hirshfeld surface analyses conﬁrm the importance of H...H contacts in the molecular packing of each of (I) and (II), and in the case of (I), highlight the importance of short methoxy-H...H(butyl) contacts between layers. 2018 Article PeerReviewed text en http://eprints.sunway.edu.my/753/1/Tiekink%20Crystal%20structures%20and%20Hirshfeld.pdf Mohamad Rapidah, and Awang Normah, and Kamaludin Nurul Farahana, and Jotani, Mukesh M. and Tiekink, Edward R. T. * (2018) Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV). Acta Crystallographica Section E Crystallographic Communications, 74 (3). pp. 302-308. ISSN 2056-9890 http://doi.org/10.1107/S2056989018001901 doi:10.1107/S2056989018001901
spellingShingle	QD Chemistry Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M. Tiekink, Edward R. T. * Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)
title	Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)
title_full	Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)
title_fullStr	Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)
title_full_unstemmed	Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)
title_short	Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)
title_sort	crystal structures and hirshfeld surface analyses of bis[n,n-bis(2-methoxyethyl)dithiocarbamato-κ2 s,s′]di-n-butyltin(iv) and [n-(2-methoxyethyl)-n-methyldithiocarbamato-κ2 s,s′]triphenyltin(iv)
topic	QD Chemistry
url	http://eprints.sunway.edu.my/753/ http://eprints.sunway.edu.my/753/ http://eprints.sunway.edu.my/753/ http://eprints.sunway.edu.my/753/1/Tiekink%20Crystal%20structures%20and%20Hirshfeld.pdf

Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)

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