1-Anilino-5-methyl-1H-1,2,3-triazole-4-carbaldehyde
The title compound, C10H10N4O, is twisted about the Nring-Namine bond with the dihedral angle between the 1,2,3-triazolyl and N-bound phenyl rings being 79.14 (9)°. The C-bound aldehyde group is coplanar with the triazolyl ring, with the N-C-C-O torsion angle being 3.5 (3)°. While coplanar, the alde...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2016
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| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/664/ http://eprints.sunway.edu.my/664/1/IUCrData%202016%201%20x160038.pdf |
| Summary: | The title compound, C10H10N4O, is twisted about the Nring-Namine bond with the dihedral angle between the 1,2,3-triazolyl and N-bound phenyl rings being 79.14 (9)°. The C-bound aldehyde group is coplanar with the triazolyl ring, with the N-C-C-O torsion angle being 3.5 (3)°. While coplanar, the aldehyde O atom is orientated in the opposite direction to the triazolyl-bound methyl group. The most prominent feature of the molecular packing is the formation of zigzag chains (glide symmetry) along the b axis and mediated by amine-N-H...N(triazolyl) hydrogen bonds. The chains are connected into supramolecular layers by phenyl- and methyl-C-H...O(aldehyde) interactions, with phenyl groups projecting to either side. Layers stack along the c axis with no directional interactions between them. |
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