[1-(2,5-Dichloroanilino)-5-methyl-1H-1,2,3-triazol-4-yl]methanol
In the title compound, C10H10Cl2N4O, the hydroxy group and benzene ring are disposed to opposite sides of the central 1,2,3-triazolyl ring. The dihedral angle between the five- and six-membered rings is 87.51 (12)°, and the C-O bond of the hydroxy group lies almost normal to the plane of the 5-mem...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2016
|
| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/661/ http://eprints.sunway.edu.my/661/1/IUCrData%202016%201%20x152447.pdf |
| Summary: | In the title compound, C10H10Cl2N4O, the hydroxy group and benzene ring are disposed to opposite sides of the central 1,2,3-triazolyl ring. The dihedral angle between the five- and six-membered rings is 87.51 (12)°, and the C-O bond of the hydroxy group lies almost normal to the plane of the 5-membered ring [N-C-C-O = -93.2 (2)°]. An intramolecular amino-N-H...Cl hydrogen bond is noted. In the extended structure, supramolecular layers in the ab plane are formed via hydroxy-O-H...N(ring) and amine-N-H...O(hydroxy) hydrogen bonds. The layers are connected along the c axis by [pi]-[pi] contacts between benzene rings [inter-centroid distance = 3.7789 (13) Å] and by C-Cl...[pi] interactions. |
|---|