Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the mol...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016
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| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/660/ http://eprints.sunway.edu.my/660/1/IUCrData%202016%201%20x152429.pdf |
| _version_ | 1848801871852994560 |
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| author | Ehsan, Muhammad Ali Muhammad Mazhar, Tiekink, Edward R. T. * |
| author_facet | Ehsan, Muhammad Ali Muhammad Mazhar, Tiekink, Edward R. T. * |
| author_sort | Ehsan, Muhammad Ali |
| building | SU Institutional Repository |
| collection | Online Access |
| description | The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methylene-C-H...S interactions. These are connected into layers parallel to (10-2) via weak methyl-C-H...[pi](phenyl) interactions. |
| first_indexed | 2025-11-14T21:14:21Z |
| format | Article |
| id | sunway-660 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:14:21Z |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-6602020-10-07T09:56:11Z http://eprints.sunway.edu.my/660/ Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) Ehsan, Muhammad Ali Muhammad Mazhar, Tiekink, Edward R. T. * QD Chemistry The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methylene-C-H...S interactions. These are connected into layers parallel to (10-2) via weak methyl-C-H...[pi](phenyl) interactions. International Union of Crystallography 2016 Article PeerReviewed text en cc_by_nc_nd http://eprints.sunway.edu.my/660/1/IUCrData%202016%201%20x152429.pdf Ehsan, Muhammad Ali and Muhammad Mazhar, and Tiekink, Edward R. T. * (2016) Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II). IUCrData, 1 (1). x152429. ISSN 2414-3146 http://dx.doi.org/10.1107/S2414314615024293 doi:10.1107/S2414314615024293 |
| spellingShingle | QD Chemistry Ehsan, Muhammad Ali Muhammad Mazhar, Tiekink, Edward R. T. * Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_full | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_fullStr | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_full_unstemmed | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_short | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_sort | bis(n-benzyl-n-methyldithiocarbamato-κ2s,s′)(pyridine-κn)cadmium(ii) |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/660/ http://eprints.sunway.edu.my/660/ http://eprints.sunway.edu.my/660/ http://eprints.sunway.edu.my/660/1/IUCrData%202016%201%20x152429.pdf |