Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the mol...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2016
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| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/660/ http://eprints.sunway.edu.my/660/1/IUCrData%202016%201%20x152429.pdf |
| Summary: | The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methylene-C-H...S interactions. These are connected into layers parallel to (10-2) via weak methyl-C-H...[pi](phenyl) interactions. |
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