Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy) hydrogen bonding. The structure contrasts that of...
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De Gruyter
2016
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| Online Access: | http://eprints.sunway.edu.my/658/ http://eprints.sunway.edu.my/658/1/Z.%20Kristallogr.%202016%20231%20403.pdf |
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| author | Jotani, Mukesh M. Tan, Yee Seng * Tiekink, Edward R. T. * |
| author_facet | Jotani, Mukesh M. Tan, Yee Seng * Tiekink, Edward R. T. * |
| author_sort | Jotani, Mukesh M. |
| building | SU Institutional Repository |
| collection | Online Access |
| description | The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy) hydrogen bonding. The structure contrasts that of Hg[S2CN(CH2CH2OH)2]2 (2; this is a literature structure) in which square planar units are connected into supramolecular chains via Hg···S secondary bonding; chains are connected in the crystal structure by hydroxyl-O–H···O(hydroxy) hydrogen bonding. A Hirshfeld surface analysis on 1 and 2 reveal the influence of O–H···O and Hg···S interactions on the molecular packing as well as the distinctive interactions, such as C–H···S interactions in 1 and C–H···π (HgS2C) contacts in 2. A bibliographic survey shows the different structural motifs observed for 1 and 2 are complimented by an additional five motifs for binary mercury(II) dithiocarbamates revealing a fascinating structural diversity for this class of compound. |
| first_indexed | 2025-11-14T21:14:20Z |
| format | Article |
| id | sunway-658 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:14:20Z |
| publishDate | 2016 |
| publisher | De Gruyter |
| recordtype | eprints |
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| spelling | sunway-6582020-10-07T09:49:46Z http://eprints.sunway.edu.my/658/ Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis Jotani, Mukesh M. Tan, Yee Seng * Tiekink, Edward R. T. * QD Chemistry The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy) hydrogen bonding. The structure contrasts that of Hg[S2CN(CH2CH2OH)2]2 (2; this is a literature structure) in which square planar units are connected into supramolecular chains via Hg···S secondary bonding; chains are connected in the crystal structure by hydroxyl-O–H···O(hydroxy) hydrogen bonding. A Hirshfeld surface analysis on 1 and 2 reveal the influence of O–H···O and Hg···S interactions on the molecular packing as well as the distinctive interactions, such as C–H···S interactions in 1 and C–H···π (HgS2C) contacts in 2. A bibliographic survey shows the different structural motifs observed for 1 and 2 are complimented by an additional five motifs for binary mercury(II) dithiocarbamates revealing a fascinating structural diversity for this class of compound. De Gruyter 2016-07 Article PeerReviewed text en http://eprints.sunway.edu.my/658/1/Z.%20Kristallogr.%202016%20231%20403.pdf Jotani, Mukesh M. and Tan, Yee Seng * and Tiekink, Edward R. T. * (2016) Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis. Zeitschrift für Kristallographie - Crystalline Materials, 231 (7). pp. 403-413. ISSN 2194-4946 http://dx.doi.org/10.1515/zkri-2016-1943 doi:10.1515/zkri-2016-1943 |
| spellingShingle | QD Chemistry Jotani, Mukesh M. Tan, Yee Seng * Tiekink, Edward R. T. * Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis |
| title | Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis |
| title_full | Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis |
| title_fullStr | Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis |
| title_short | Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis |
| title_sort | bis[bis(n-2-hydroxyethyl,n-isopropyl-dithiocarbamato)mercury(ii)]2: crystal structure and hirshfeld surface analysis |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/658/ http://eprints.sunway.edu.my/658/ http://eprints.sunway.edu.my/658/ http://eprints.sunway.edu.my/658/1/Z.%20Kristallogr.%202016%20231%20403.pdf |