[μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis
In the title cluster complex hexane solvate, [Ru6(C30H32P2)(CO)22]·C6H14, two Ru3(CO)11 fragments are linked by a Ph2P(CH2)6PPh2 bridge with the P atoms equatorially disposed with respect to the Ru3 triangle in each case; the hexane solvent molecule is statistically disordered. The Ru...Ru distance...
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| Language: | English |
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International Union of Crystallography
2017
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| Online Access: | http://eprints.sunway.edu.my/628/ http://eprints.sunway.edu.my/628/1/Acta%20Cryst.%20%282017%29.%20E73%2C%201652.pdf |
| _version_ | 1848801864451096576 |
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| author | Omar Shawkataly, Siti Syaida Sirat, Jotani, Mukesh M. Tiekink, Edward R. T. * |
| author_facet | Omar Shawkataly, Siti Syaida Sirat, Jotani, Mukesh M. Tiekink, Edward R. T. * |
| author_sort | Omar Shawkataly, |
| building | SU Institutional Repository |
| collection | Online Access |
| description | In the title cluster complex hexane solvate, [Ru6(C30H32P2)(CO)22]·C6H14, two Ru3(CO)11 fragments are linked by a Ph2P(CH2)6PPh2 bridge with the P atoms equatorially disposed with respect to the Ru3 triangle in each case; the hexane solvent molecule is statistically disordered. The Ru...Ru distances span a relatively narrow range, i.e. 2.8378 (4) to 2.8644 (4) Å. The hexyl chain within the bridge has an all-trans conformation. In the molecular packing, C—H...O interactions between cluster molecules, and between cluster and hexane solvent molecules lead to a three-dimensional architecture. In addition, there are a large number of C[triple bond]O...π(arene) interactions in the crystal. The importance of the carbonyl groups in establishing the packing is emphasized by the contribution of 53.4% to the Hirshfeld surface by O...H/H...O contacts. |
| first_indexed | 2025-11-14T21:14:14Z |
| format | Article |
| id | sunway-628 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:14:14Z |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-6282020-10-07T09:30:35Z http://eprints.sunway.edu.my/628/ [μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis Omar Shawkataly, Siti Syaida Sirat, Jotani, Mukesh M. Tiekink, Edward R. T. * QD Chemistry In the title cluster complex hexane solvate, [Ru6(C30H32P2)(CO)22]·C6H14, two Ru3(CO)11 fragments are linked by a Ph2P(CH2)6PPh2 bridge with the P atoms equatorially disposed with respect to the Ru3 triangle in each case; the hexane solvent molecule is statistically disordered. The Ru...Ru distances span a relatively narrow range, i.e. 2.8378 (4) to 2.8644 (4) Å. The hexyl chain within the bridge has an all-trans conformation. In the molecular packing, C—H...O interactions between cluster molecules, and between cluster and hexane solvent molecules lead to a three-dimensional architecture. In addition, there are a large number of C[triple bond]O...π(arene) interactions in the crystal. The importance of the carbonyl groups in establishing the packing is emphasized by the contribution of 53.4% to the Hirshfeld surface by O...H/H...O contacts. International Union of Crystallography 2017 Article PeerReviewed text en cc_by_nc_nd http://eprints.sunway.edu.my/628/1/Acta%20Cryst.%20%282017%29.%20E73%2C%201652.pdf Omar Shawkataly, and Siti Syaida Sirat, and Jotani, Mukesh M. and Tiekink, Edward R. T. * (2017) [μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E Crystallographic Communications, 73 (11). pp. 1652-1657. ISSN 2056-9890 http://dx.doi.org/10.1107/S2056989017014517 doi:10.1107/S2056989017014517 |
| spellingShingle | QD Chemistry Omar Shawkataly, Siti Syaida Sirat, Jotani, Mukesh M. Tiekink, Edward R. T. * [μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis |
| title | [μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis |
| title_full | [μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis |
| title_fullStr | [μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | [μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis |
| title_short | [μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis |
| title_sort | [μ2-bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 ru—ru)] hexane monosolvate: crystal structure and hirshfeld surface analysis |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/628/ http://eprints.sunway.edu.my/628/ http://eprints.sunway.edu.my/628/ http://eprints.sunway.edu.my/628/1/Acta%20Cryst.%20%282017%29.%20E73%2C%201652.pdf |