Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes
This comprehensive review summarizes recent advances in the synthesis and coordination chemistry of dibenzotetraaza[14]annulenes (DBTAAs) reported between 2010 and 2021. Owing to the smaller N4 donor cavity compared to that of the porphyrin core, it is not surprising that DBTAA offers versatile and...
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| Format: | Article |
| Language: | English |
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Elsevier
2022
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| Online Access: | http://eprints.sunway.edu.my/2097/ http://eprints.sunway.edu.my/2097/1/ccr%202022%20214672.pdf |
| _version_ | 1848802197666529280 |
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| author | Abdul, Qaiyum Ramle Tiekink, Edward R. T. * Wan, Jefrey Basirun |
| author_facet | Abdul, Qaiyum Ramle Tiekink, Edward R. T. * Wan, Jefrey Basirun |
| author_sort | Abdul, Qaiyum Ramle |
| building | SU Institutional Repository |
| collection | Online Access |
| description | This comprehensive review summarizes recent advances in the synthesis and coordination chemistry of dibenzotetraaza[14]annulenes (DBTAAs) reported between 2010 and 2021. Owing to the smaller N4 donor cavity compared to that of the porphyrin core, it is not surprising that DBTAA offers versatile and unique coordination modes towards metal ions. The structural modification of the DBTAA core allows for the fine-tuning of their spectroscopic properties. DBTAA and derivatives have been utilized across a wide range of research disciplines such as in electronic devices and biological assays. The feasible preparation of ligands and their metal complexes suggests DBTAAs as potential alternatives to porphyrins. |
| first_indexed | 2025-11-14T21:19:31Z |
| format | Article |
| id | sunway-2097 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:19:31Z |
| publishDate | 2022 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-20972022-06-24T07:29:19Z http://eprints.sunway.edu.my/2097/ Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes Abdul, Qaiyum Ramle Tiekink, Edward R. T. * Wan, Jefrey Basirun QD Chemistry This comprehensive review summarizes recent advances in the synthesis and coordination chemistry of dibenzotetraaza[14]annulenes (DBTAAs) reported between 2010 and 2021. Owing to the smaller N4 donor cavity compared to that of the porphyrin core, it is not surprising that DBTAA offers versatile and unique coordination modes towards metal ions. The structural modification of the DBTAA core allows for the fine-tuning of their spectroscopic properties. DBTAA and derivatives have been utilized across a wide range of research disciplines such as in electronic devices and biological assays. The feasible preparation of ligands and their metal complexes suggests DBTAAs as potential alternatives to porphyrins. Elsevier 2022-10-15 Article PeerReviewed text en cc_by_nc_nd_4 http://eprints.sunway.edu.my/2097/1/ccr%202022%20214672.pdf Abdul, Qaiyum Ramle and Tiekink, Edward R. T. * and Wan, Jefrey Basirun (2022) Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes. Coordination Chemistry Reviews, 469. p. 214672. ISSN 00108545 https://doi.org/10.1016/j.ccr.2022.214672 doi:10.1016/j.ccr.2022.214672 |
| spellingShingle | QD Chemistry Abdul, Qaiyum Ramle Tiekink, Edward R. T. * Wan, Jefrey Basirun Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes |
| title | Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes |
| title_full | Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes |
| title_fullStr | Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes |
| title_full_unstemmed | Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes |
| title_short | Synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes |
| title_sort | synthesis, functionalization and coordination chemistry of dibenzotetraaza[14]annulenes |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/2097/ http://eprints.sunway.edu.my/2097/ http://eprints.sunway.edu.my/2097/ http://eprints.sunway.edu.my/2097/1/ccr%202022%20214672.pdf |