Unusual {⋯HNC2O⋯HCnO}, n = 1 or 2, synthons predominate in the molecular packing of one-dimensional coordination polymers, {Cd[S2P(OR)2]2(3LH2)}n, for R = Me and Et, but are precluded when R = i-Pr; 3LH2 = N,N′-bis(3-pyridylmethyl)oxalamide

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Unusual {⋯HNC2O⋯HCnO}, n = 1 or 2, synthons predominate in the molecular packing of one-dimensional coordination polymers, {Cd[S2P(OR)2]2(3LH2)}n, for R = Me and Et, but are precluded when R = i-Pr; 3LH2 = N,N′-bis(3-pyridylmethyl)oxalamide

Linear, one-dimensional coordination polymers, {Cd[S2P(OR)2]2(3LH2)}n, for R = Me (1), Et(2) and i-Pr(3) have been fully characterised by a variety of physiochemical, spectroscopic, crystallographic and computational techniques. Two-dimensional layers are apparent in the crystals of 1 and 2, being m...

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Bibliographic Details
Main Authors:	Tan, Yee Seng, Yeo, Chien Ing, Kwong, Huey Chong, Tiekink, Edward R. T.
Format:	Article
Language:	English
Published:	Royal Society of Chemistry 2022
Subjects:	QD Chemistry
Online Access:	http://eprints.sunway.edu.my/2014/ http://eprints.sunway.edu.my/2014/1/Unusual%20HNC2O.pdf

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