The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs
A review of the coordination chemistry along with the structural features of heavy element complexes of dithiocarbimate di-anions in the form of [(R)C=NCS2]2− for R = CN, alkyl, and aryl are described. This class of compound is far less studied compared with the well-explored dithiocarbamate mono-an...
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MDPI
2021
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| Online Access: | http://eprints.sunway.edu.my/1852/ http://eprints.sunway.edu.my/1852/1/Tiekink%20Coordination%20Chemistry%20inorganics%202021%209%2071.pdf |
| _version_ | 1848802148775624704 |
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| author | Heard, Peter * Tan, Yee Seng * Yeo, Chien Ing * Tiekink, Edward R. T. * |
| author_facet | Heard, Peter * Tan, Yee Seng * Yeo, Chien Ing * Tiekink, Edward R. T. * |
| author_sort | Heard, Peter * |
| building | SU Institutional Repository |
| collection | Online Access |
| description | A review of the coordination chemistry along with the structural features of heavy element complexes of dithiocarbimate di-anions in the form of [(R)C=NCS2]2− for R = CN, alkyl, and aryl are described. This class of compound is far less studied compared with the well-explored dithiocarbamate mono-anions formulated as [R(R’)NCS2]− for R/R’ = H, alkyl, and aryl. The coordination chemistry of dithiocarbimate di-anions is dominated by a S,S-chelating mode; rare examples of alternative modes of coordination are evident. When comparisons are available, the structural motifs adopted by metal dithiocarbimate complexes match those found for their dithiocarbamate analogs, with only small, non-systematic variations in the M–S bond lengths |
| first_indexed | 2025-11-14T21:18:45Z |
| format | Article |
| id | sunway-1852 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:18:45Z |
| publishDate | 2021 |
| publisher | MDPI |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-18522021-09-22T09:00:49Z http://eprints.sunway.edu.my/1852/ The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs Heard, Peter * Tan, Yee Seng * Yeo, Chien Ing * Tiekink, Edward R. T. * QD Chemistry A review of the coordination chemistry along with the structural features of heavy element complexes of dithiocarbimate di-anions in the form of [(R)C=NCS2]2− for R = CN, alkyl, and aryl are described. This class of compound is far less studied compared with the well-explored dithiocarbamate mono-anions formulated as [R(R’)NCS2]− for R/R’ = H, alkyl, and aryl. The coordination chemistry of dithiocarbimate di-anions is dominated by a S,S-chelating mode; rare examples of alternative modes of coordination are evident. When comparisons are available, the structural motifs adopted by metal dithiocarbimate complexes match those found for their dithiocarbamate analogs, with only small, non-systematic variations in the M–S bond lengths MDPI 2021-09 Article PeerReviewed text en cc_by_nc_nd_4 http://eprints.sunway.edu.my/1852/1/Tiekink%20Coordination%20Chemistry%20inorganics%202021%209%2071.pdf Heard, Peter * and Tan, Yee Seng * and Yeo, Chien Ing * and Tiekink, Edward R. T. * (2021) The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs. Inorganics, 9 (9). p. 71. ISSN 2304-6740 http://doi.org/10.3390/inorganics9090071 doi:10.3390/inorganics9090071 |
| spellingShingle | QD Chemistry Heard, Peter * Tan, Yee Seng * Yeo, Chien Ing * Tiekink, Edward R. T. * The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs |
| title | The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs |
| title_full | The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs |
| title_fullStr | The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs |
| title_full_unstemmed | The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs |
| title_short | The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs |
| title_sort | coordination chemistry of imidomethanedithiolate di-anions: a structural comparison with their dithiocarbamate analogs |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/1852/ http://eprints.sunway.edu.my/1852/ http://eprints.sunway.edu.my/1852/ http://eprints.sunway.edu.my/1852/1/Tiekink%20Coordination%20Chemistry%20inorganics%202021%209%2071.pdf |