Crystal structure analysis and supramolecular association in ethyl N-[amino(iminio)methyl]carbamate dichloride hemi-hydrate

QR Code

Crystal structure analysis and supramolecular association in ethyl N-[amino(iminio)methyl]carbamate dichloride hemi-hydrate

X-ray crystallography on [EtOC(=O)N(H)C(=N+H2)NH2]Cl·½H2O (1) shows the asymmetric unit to comprise two independent cations, two chloride anions and crystal water. The main conformational difference between the cations is seen in the relative orientation of the ethyl groups; geometry-optimisation co...

Full description

Bibliographic Details
Main Authors:	Bamigboye, C, Abbo, H. S., Kwong, Huey Chong, Tan, Sang Loon , Tiekink, Edward R. T. , Kamounah, F. S., Titinchi, S. J. J.
Format:	Article
Language:	English
Published:	Oldenbough Verlag 2021
Subjects:	QD Chemistry
Online Access:	http://eprints.sunway.edu.my/1830/ http://eprints.sunway.edu.my/1830/1/Tiekink%20Crystal%20Structure%20acc_z%20kristallogr%202021%20236%20187.pdf

Similar Items

2-[Carbamothioyl(2-hydroxyethyl)amino]ethyl benzoate: crystal structure, Hirshfeld surface analysis and computational study
by: Tan, Sang Loon *, et al.
Published: (2020)

Ethyl 3-amino-4-[(2-hydroxyethyl)amino]benzoate
by: Arumugam, Natarajan, et al.
Published: (2010)

Paraquat dichloride detection from forensic blowfly samples
by: Wan Mohd Asyraf Wan Mahmood,, et al.
Published: (2015)

Optoelectronic performance of Jatropha oil-derived poly(ethyl carbamate) gel polymer electrolyte as quasi-solid-state solution for photoelectrochemical cells
by: Chai, K.L, et al.
Published: (2024)

Asymmetric pentafulvene carbometalation-access to enantiopure titanocene dichlorides of biological relevance
by: Cini, Melchior, et al.
Published: (2015)

An overview on biodegradation of carbamate pesticides by soil bacteria
by: Mustapha, Mohammed Umar, et al.
Published: (2019)

The development of efficient hemi-autotrophic carbon fixation in Escherichia Coli
by: Hendriks, Rudolf Martinus Antonius
Published: (2023)

(Tris{2-[(5-chloro-2-oxidobenzylidene-κO)amino-κN]ethyl}amine-κN)ytterbium(III): crystal structure and Hirshfeld surface analysis
by: Lee, See Mun *, et al.
Published: (2016)

Acetylcholinesterase from Puntius javanicus for the detection of carbamates and organophosphates
by: Sabullah, Mohd Khalizan, et al.
Published: (2015)

Quasi-Static Axial Crushing Behaviour of Composite Hemi-Spherical Shells
by: Saleh, Mhfud Ahmed Masoud
Published: (2004)

How many types of fungal & oomycete phytopathogens are there? Catastrophy for the bio/hemi/necrotroph divisions
by: Hane, J., et al.
Published: (2018)

Zwitterionic 1-{(1E)-[(4-hydroxyphenyl)iminio]methyl}naphthalen-2-olate: crystal structure and Hirshfeld surface analysis
by: Devika, Bhai R., et al.
Published: (2017)

Pharmacokinetics And Metabolism Studies Of Antifilarial Drugs Derivatives Of Benzimidazole Carbamate
by: Ramanathan, Surash
Published: (1996)

Characterization And Effect Of Sn(Iv) Chlorin E6 Dichloride Trisodium Salt In Photodynamic Therapy
by: Al-Khaza'leh, Khaled Abdu Bdaiwi
Published: (2009)

Validation of a reverse-phase high-performance liquid chromatography method for the determination of amino acids in gelatins by application of 6-aminoquinolyl-N-hydroxysuccinimidyl carbamate reagent
by: Mohd Ismail, Azilawati, et al.
Published: (2014)

In Vitro Study Of The Effect Of Corn Silk On Glucose Uptake By Isolated Rat Hemi-Diaphragm
by: Nour, A. H., et al.
Published: (2014)

Cuprate addition to a 6-substituted pentafulvene: preparation of sec-alkyl substituted titanocene dichlorides and their biological activity
by: Cini, Melchior, et al.
Published: (2013)

Characterization And Effect Of SN (IV) Chlorin E6 Dichloride Trisodium Salt In Photodynamic Therapy[QC1].
by: Al-Khaza'leh, Khaled Abdu Bdaiwi
Published: (2009)

Determination of Carbamate and Organophosphorus Pesticides in Vegetable Samples and the Efficiency of Gamma-Radiation in Their Removal
by: Chowdhury, Muhammed Alamgir Zaman, et al.
Published: (2014)

4-[(1E)-({[(Benzylsulfanyl)methanethioyl]amino}imino)methyl]benzene-1,3-diol chloroform hemisolvate: crystal structure, Hirshfeld surface analysis and computational study
by: Khairuanuar, N. L., et al.
Published: (2020)

Enzyme inhibition-based biosensors using Acetylcholinesterase from Monopterus albus for detection of carbamates contamination
by: Khalidi, S. A. M., et al.
Published: (2022)

Hydration, Hydration, Hydration
by: Miller, Veronica, et al.
Published: (2010)

Biodegradation of carbamate pesticide (carbofuran) by indigenous bacteria isolated from selected agricultural soil
by: Mustapha, Mohammed Umar
Published: (2020)

Supramolecular nesting of cyclic polymers
by: Kondratuk, Dmitry V., et al.
Published: (2015)

Supramolecular and Materials Applications of Tetrazines
by: Black, Martin
Published: (2025)

Estimation of uncertainty from method validation data: application to a reverse-phase high-performance liquid chromatography method for the determination of amino acids in gelatin using 6-aminoquinolyl-N-hydroxysuccinimidyl carbamate reagent
by: Mohd Ismail, Azilawati, et al.
Published: (2016)

Profiling of Cholinesterase extracted from the brain tissue of Diodon hystrix and its inhibition reaction towards carbamates
by: Haris, Akid, et al.
Published: (2020)

Profiling of cholinesterase extracted from the brain tissue of Diodon hystrix and its inhibition reaction towards carbamates
by: Haris, Akid, et al.
Published: (2020)

Supramolecular association in the triclinic (Z′ = 1) and monoclinic (Z′ = 4) polymorphs of 4-(4-acetylphenyl)piperazin-1-ium 2-amino4-nitrobenzoate
by: Jotani, Mukesh M., et al.
Published: (2019)

Synthesis of molecular species for supramolecular assembly
by: Taleb, Nassiba
Published: (2011)

Supramolecular associations peculiar to coordination complexes
by: Tiekink, Edward R. T. *
Published: (2017)

A Supramolecular Ice Growth Inhibitor
by: Drori, R., et al.
Published: (2016)

Supramolecular designs based on hydrogen bonding.
by: Ibrahim, Abdul Razak

Tuning the electrical conductance of metalloporphyrin supramolecular wires
by: Noori, Mohammed, et al.
Published: (2016)

Developing a self-healing supramolecular nucleoside hydrogel
by: Skilling, Kathryn J., et al.
Published: (2016)

Non-covalent interactions involving remote substituents influence the topologies of supramolecular chains featuring hydroxyl-O–H⋯O(hydroxyl) hydrogen bonding in crystals of (HOCH2CH2)2NC(S)N(H)(C6H4Y-4) for Y = H, Me, Cl and NO2
by: Tan, Sang Loon *, et al.
Published: (2021)

Supramolecular networks stabilise and functionalise black phosphorus
by: Korolkov, Vladimir V., et al.
Published: (2017)

The supramolecular chemistry of handcuff rotaxanes and deteriorating leather
by: Tarnowska, Marysia
Published: (2023)

Tuning the electrical conductance of metalloporphyrin supramolecular wires
by: Noori, M., et al.
Published: (2016)

Preparation and Characterisation of Photoactive Supramolecular Soft Materials
by: Smith, Shaun
Published: (2024)