4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid
The synthesis and spectroscopic characterization of the glutaric acid-amide derivative, 2,4-Cl2C6H3N(H)C(=O)(CH2)3C(=O)OH (1), are described. The X-ray crystal structure determination of (1) shows the backbone of the molecule to be kinked about the methylene-C–N(amide) bond as seen in the C(p)–N–C(m...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI
2021
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| Online Access: | http://eprints.sunway.edu.my/1780/ http://eprints.sunway.edu.my/1780/1/Tiekink%20molbank-2021-m1227.pdf |
| _version_ | 1848802132797423616 |
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| author | Hanifa, B. Sirajuddin, M. Ullah, Z. Sumera, M. Lee, See Mun * Lo, Kong Mun * Tiekink, Edward R. T. * |
| author_facet | Hanifa, B. Sirajuddin, M. Ullah, Z. Sumera, M. Lee, See Mun * Lo, Kong Mun * Tiekink, Edward R. T. * |
| author_sort | Hanifa, B. |
| building | SU Institutional Repository |
| collection | Online Access |
| description | The synthesis and spectroscopic characterization of the glutaric acid-amide derivative, 2,4-Cl2C6H3N(H)C(=O)(CH2)3C(=O)OH (1), are described. The X-ray crystal structure determination of (1) shows the backbone of the molecule to be kinked about the methylene-C–N(amide) bond as seen in the C(p)–N–C(m)–C(m) torsion angle of −157.0(2)°; m = methylene and p = phenyl. An additional twist in the molecule is noted between the amide and phenyl groups as reflected in the C(m)–N–C(p)–C(p) torsion angle of 138.2(2)°. The most prominent feature of the molecular packing is the formation of supramolecular tapes assembled through carboxylic acid-O–H…O(carbonyl) and amide-N–H…O(amide) hydrogen bonding. |
| first_indexed | 2025-11-14T21:18:30Z |
| format | Article |
| id | sunway-1780 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:18:30Z |
| publishDate | 2021 |
| publisher | MDPI |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-17802021-08-27T06:14:24Z http://eprints.sunway.edu.my/1780/ 4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid Hanifa, B. Sirajuddin, M. Ullah, Z. Sumera, M. Lee, See Mun * Lo, Kong Mun * Tiekink, Edward R. T. * QD Chemistry The synthesis and spectroscopic characterization of the glutaric acid-amide derivative, 2,4-Cl2C6H3N(H)C(=O)(CH2)3C(=O)OH (1), are described. The X-ray crystal structure determination of (1) shows the backbone of the molecule to be kinked about the methylene-C–N(amide) bond as seen in the C(p)–N–C(m)–C(m) torsion angle of −157.0(2)°; m = methylene and p = phenyl. An additional twist in the molecule is noted between the amide and phenyl groups as reflected in the C(m)–N–C(p)–C(p) torsion angle of 138.2(2)°. The most prominent feature of the molecular packing is the formation of supramolecular tapes assembled through carboxylic acid-O–H…O(carbonyl) and amide-N–H…O(amide) hydrogen bonding. MDPI 2021-06 Article PeerReviewed text en cc_by_nc_4 http://eprints.sunway.edu.my/1780/1/Tiekink%20molbank-2021-m1227.pdf Hanifa, B. and Sirajuddin, M. and Ullah, Z. and Sumera, M. and Lee, See Mun * and Lo, Kong Mun * and Tiekink, Edward R. T. * (2021) 4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid. Molbank (M1227). ISSN 1422-8599 https://doi.org/10.3390/M1227 https://doi.org/10.3390/M1227 |
| spellingShingle | QD Chemistry Hanifa, B. Sirajuddin, M. Ullah, Z. Sumera, M. Lee, See Mun * Lo, Kong Mun * Tiekink, Edward R. T. * 4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid |
| title | 4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid |
| title_full | 4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid |
| title_fullStr | 4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid |
| title_full_unstemmed | 4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid |
| title_short | 4-[(2,4-Dichlorophenyl)carbamoyl]butanoic Acid |
| title_sort | 4-[(2,4-dichlorophenyl)carbamoyl]butanoic acid |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/1780/ http://eprints.sunway.edu.my/1780/ http://eprints.sunway.edu.my/1780/ http://eprints.sunway.edu.my/1780/1/Tiekink%20molbank-2021-m1227.pdf |