4-[(4-Chlorophenyl)carbamoyl]butanoic Acid
The X-ray crystal structure determination of the glutaric acid-amide derivative, 4-ClC6H4N(H)C(=O)(CH2)3C(=O)OH (1), is described. The backbone of the molecule adopts an extended, all-trans configuration but the terminal carboxylic acid and phenyl resides are twisted out of the plane through the bri...
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| Format: | Article |
| Language: | English |
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MDPI
2021
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| Online Access: | http://eprints.sunway.edu.my/1757/ http://eprints.sunway.edu.my/1757/1/Tiekink%204-4%20molbank-2021-m1209.pdf |
| _version_ | 1848802127414034432 |
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| author | Hanifa, B. Sirajuddin, M. Bari, A Lee, See Mun * Lo, Kong Mun * Tiekink, Edward R. T. * |
| author_facet | Hanifa, B. Sirajuddin, M. Bari, A Lee, See Mun * Lo, Kong Mun * Tiekink, Edward R. T. * |
| author_sort | Hanifa, B. |
| building | SU Institutional Repository |
| collection | Online Access |
| description | The X-ray crystal structure determination of the glutaric acid-amide derivative, 4-ClC6H4N(H)C(=O)(CH2)3C(=O)OH (1), is described. The backbone of the molecule adopts an extended, all-trans configuration but the terminal carboxylic acid and phenyl resides are twisted out of the plane through the bridging atoms, as seen in the torsion angles of O(carboxylic acid)–C(m)–C(m)–C(m) [13.9(5)°] and C(m)–N–C(p)–C(p) [47.1(4)°]; m = methylene and p = phenyl. The most striking feature of the molecular packing is the formation of supramolecular tapes mediated by carboxylic acid-O–H⋯O(carbonyl) and amide-N–H⋯O(amide) hydrogen bonding |
| first_indexed | 2025-11-14T21:18:24Z |
| format | Article |
| id | sunway-1757 |
| institution | Sunway University |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T21:18:24Z |
| publishDate | 2021 |
| publisher | MDPI |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | sunway-17572021-05-12T06:42:42Z http://eprints.sunway.edu.my/1757/ 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid Hanifa, B. Sirajuddin, M. Bari, A Lee, See Mun * Lo, Kong Mun * Tiekink, Edward R. T. * QD Chemistry The X-ray crystal structure determination of the glutaric acid-amide derivative, 4-ClC6H4N(H)C(=O)(CH2)3C(=O)OH (1), is described. The backbone of the molecule adopts an extended, all-trans configuration but the terminal carboxylic acid and phenyl resides are twisted out of the plane through the bridging atoms, as seen in the torsion angles of O(carboxylic acid)–C(m)–C(m)–C(m) [13.9(5)°] and C(m)–N–C(p)–C(p) [47.1(4)°]; m = methylene and p = phenyl. The most striking feature of the molecular packing is the formation of supramolecular tapes mediated by carboxylic acid-O–H⋯O(carbonyl) and amide-N–H⋯O(amide) hydrogen bonding MDPI 2021-05 Article PeerReviewed text en cc_by_nc_4 http://eprints.sunway.edu.my/1757/1/Tiekink%204-4%20molbank-2021-m1209.pdf Hanifa, B. and Sirajuddin, M. and Bari, A and Lee, See Mun * and Lo, Kong Mun * and Tiekink, Edward R. T. * (2021) 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid. Molbank, 2021 (2). M1209. ISSN 1422-8599 http://doi.org/10.3390/M1209 doi:10.3390/M1209 |
| spellingShingle | QD Chemistry Hanifa, B. Sirajuddin, M. Bari, A Lee, See Mun * Lo, Kong Mun * Tiekink, Edward R. T. * 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid |
| title | 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid |
| title_full | 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid |
| title_fullStr | 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid |
| title_full_unstemmed | 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid |
| title_short | 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid |
| title_sort | 4-[(4-chlorophenyl)carbamoyl]butanoic acid |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/1757/ http://eprints.sunway.edu.my/1757/ http://eprints.sunway.edu.my/1757/ http://eprints.sunway.edu.my/1757/1/Tiekink%204-4%20molbank-2021-m1209.pdf |