Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii

Superparamagnetic magnetite nanocomposites (Fe3O4-NCs) were successfully synthesized, which comprised of montmorillonite (MMT) as matrix support, Kappaphycus alvarezii (SW) as bio-stabilizer and Fe3O4 as filler in the composites to form MMT/SW/Fe3O4-NCs. Nanocomposite with 0.5 g Fe3O4 (MMT/SW/0.5Fe3...

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Main Authors: Yew, Yen Pin, Shameli, Kamyar, Shaza Eva M, Yuki, Nagao, Teow, Sin Yeang *, Lee, Kar Xin, Eleen Dayana, M. I.
Format: Article
Language:English
Published: Elsevier 2019
Subjects:
Online Access:http://eprints.sunway.edu.my/1144/
http://eprints.sunway.edu.my/1144/1/Teow%20Sin%20Yeang%20potential.pdf
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author Yew, Yen Pin
Shameli, Kamyar
Shaza Eva M,
Yuki, Nagao
Teow, Sin Yeang *
Lee, Kar Xin
Eleen Dayana, M. I.
author_facet Yew, Yen Pin
Shameli, Kamyar
Shaza Eva M,
Yuki, Nagao
Teow, Sin Yeang *
Lee, Kar Xin
Eleen Dayana, M. I.
author_sort Yew, Yen Pin
building SU Institutional Repository
collection Online Access
description Superparamagnetic magnetite nanocomposites (Fe3O4-NCs) were successfully synthesized, which comprised of montmorillonite (MMT) as matrix support, Kappaphycus alvarezii (SW) as bio-stabilizer and Fe3O4 as filler in the composites to form MMT/SW/Fe3O4-NCs. Nanocomposite with 0.5 g Fe3O4 (MMT/SW/0.5Fe3O4) was selected for anticancer activity study because it revealed high crystallinity, particle size of 7.2 ± 1.7 nm with majority of spherical shape, and Ms = 5.85 emu/g with negligible coercivity. Drug loading and release studies were carried out using protocatechuic acid (PCA) as the model for anticancer drug, which showed 19% and 87% of PCA release in pH 7.4 and 4.8, respectively. Monolayer anticancer assay showed that PCA-loaded MMT/SW/Fe3O4 (MMT/SW/Fe3O4-PCA) had selectivity towards HCT116 (colorectal cancer cell line). Although MMT/SW/Fe3O4-PCA (0.64 mg/mL) showed higher IC50 than PCA (0.148 mg/mL) and MMT/SW/Fe3O4 (0.306 mg/mL, MMT/SW/Fe3O4-PCA showed more effective killing towards tumour spheroid model generated from HCT116. The IC50 for MMT/SW/Fe3O4-PCA, MMT/SW/Fe3O4 and PCA were 0.132, 0.23 and 0.55 mg/mL, respectively. This suggests the improved penetration efficiency and drug release of MMT/SW/Fe3O4-PCA towards HCT116 spheroids. Moreover, concentration that lower than 2 mg/mL MMT/SW/Fe3O4-PCA did not result any hemolysis in human blood, which suggests them to be ideal for intravenous injection. This study highlights the potential of MMT/SW/Fe3O4-NCs as drug delivery agent
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spelling sunway-11442019-12-03T09:44:18Z http://eprints.sunway.edu.my/1144/ Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii Yew, Yen Pin Shameli, Kamyar Shaza Eva M, Yuki, Nagao Teow, Sin Yeang * Lee, Kar Xin Eleen Dayana, M. I. RC0254 Neoplasms. Tumors. Oncology (including Cancer) Superparamagnetic magnetite nanocomposites (Fe3O4-NCs) were successfully synthesized, which comprised of montmorillonite (MMT) as matrix support, Kappaphycus alvarezii (SW) as bio-stabilizer and Fe3O4 as filler in the composites to form MMT/SW/Fe3O4-NCs. Nanocomposite with 0.5 g Fe3O4 (MMT/SW/0.5Fe3O4) was selected for anticancer activity study because it revealed high crystallinity, particle size of 7.2 ± 1.7 nm with majority of spherical shape, and Ms = 5.85 emu/g with negligible coercivity. Drug loading and release studies were carried out using protocatechuic acid (PCA) as the model for anticancer drug, which showed 19% and 87% of PCA release in pH 7.4 and 4.8, respectively. Monolayer anticancer assay showed that PCA-loaded MMT/SW/Fe3O4 (MMT/SW/Fe3O4-PCA) had selectivity towards HCT116 (colorectal cancer cell line). Although MMT/SW/Fe3O4-PCA (0.64 mg/mL) showed higher IC50 than PCA (0.148 mg/mL) and MMT/SW/Fe3O4 (0.306 mg/mL, MMT/SW/Fe3O4-PCA showed more effective killing towards tumour spheroid model generated from HCT116. The IC50 for MMT/SW/Fe3O4-PCA, MMT/SW/Fe3O4 and PCA were 0.132, 0.23 and 0.55 mg/mL, respectively. This suggests the improved penetration efficiency and drug release of MMT/SW/Fe3O4-PCA towards HCT116 spheroids. Moreover, concentration that lower than 2 mg/mL MMT/SW/Fe3O4-PCA did not result any hemolysis in human blood, which suggests them to be ideal for intravenous injection. This study highlights the potential of MMT/SW/Fe3O4-NCs as drug delivery agent Elsevier 2019-11-06 Article PeerReviewed text en cc_by_nc_nd_4 http://eprints.sunway.edu.my/1144/1/Teow%20Sin%20Yeang%20potential.pdf Yew, Yen Pin and Shameli, Kamyar and Shaza Eva M, and Yuki, Nagao and Teow, Sin Yeang * and Lee, Kar Xin and Eleen Dayana, M. I. (2019) Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii. International Journal of Pharmaceutics. p. 118743. ISSN 03785173 http://doi.org/10.1016/j.ijpharm.2019.118743 doi:10.1016/j.ijpharm.2019.118743
spellingShingle RC0254 Neoplasms. Tumors. Oncology (including Cancer)
Yew, Yen Pin
Shameli, Kamyar
Shaza Eva M,
Yuki, Nagao
Teow, Sin Yeang *
Lee, Kar Xin
Eleen Dayana, M. I.
Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii
title Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii
title_full Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii
title_fullStr Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii
title_full_unstemmed Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii
title_short Potential anticancer activity of protocatechuic acid loaded in montmorillonite/Fe3O4 nanocomposites stabilized by seaweed Kappaphycus alvarezii
title_sort potential anticancer activity of protocatechuic acid loaded in montmorillonite/fe3o4 nanocomposites stabilized by seaweed kappaphycus alvarezii
topic RC0254 Neoplasms. Tumors. Oncology (including Cancer)
url http://eprints.sunway.edu.my/1144/
http://eprints.sunway.edu.my/1144/
http://eprints.sunway.edu.my/1144/
http://eprints.sunway.edu.my/1144/1/Teow%20Sin%20Yeang%20potential.pdf