Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa

Solubility of CO2 in six hydroxyl ammonium ionic liquids 2-hydroxyethanaminium acetate [hea], bis(2-hydroxyethyl)ammonium acetate [bheaa], 2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium acetate [hhemea], 2-hydroxyethanaminium lactate [hel], bis(2-hydroxyethyl)ammonium lactate [bheal], 2-hydroxy-N...

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Main Authors: Kurnia, Kiki, Murugesan, Thanapalan, M.I., Abdul Mutalib, Harris, F
Format: Citation Index Journal
Language:English
Published: Elsevier 2009
Subjects:
Online Access:http://scholars.utp.edu.my/id/eprint/717/
http://scholars.utp.edu.my/id/eprint/717/1/www.sciencedirect.com_-jct.pdf
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author Kurnia, Kiki
Murugesan, Thanapalan
M.I., Abdul Mutalib
Harris, F
author_facet Kurnia, Kiki
Murugesan, Thanapalan
M.I., Abdul Mutalib
Harris, F
author_sort Kurnia, Kiki
building UTP Institutional Repository
collection Online Access
description Solubility of CO2 in six hydroxyl ammonium ionic liquids 2-hydroxyethanaminium acetate [hea], bis(2-hydroxyethyl)ammonium acetate [bheaa], 2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium acetate [hhemea], 2-hydroxyethanaminium lactate [hel], bis(2-hydroxyethyl)ammonium lactate [bheal], 2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium lactate [hhemel] at temperatures (298.15, 313.15, and 328.16) K and pressures ranging from (100 to 1600) kPa was determined. From the experimental solubility data, the Henry’s constant of CO2 for each hydroxyl ammonium ionic liquids was estimated and reported as a function of temperature. Furthermore, enthalpy and entropy of absorption were obtained from estimated Henry’s constant. The results showed that the solubility increase with increasing pressure and decrease with increasing temperature and the solubility of CO2 in these six hydroxyl ammonium ionic liquids was in sequence: [hea] > [bheaa] > [hel] > [bheal] > [hhemel] > [hhemea].
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institution Universiti Teknologi Petronas
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language English
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spelling oai:scholars.utp.edu.my:7172023-01-04T02:32:24Z http://scholars.utp.edu.my/id/eprint/717/ Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa Kurnia, Kiki Murugesan, Thanapalan M.I., Abdul Mutalib Harris, F QD Chemistry Solubility of CO2 in six hydroxyl ammonium ionic liquids 2-hydroxyethanaminium acetate [hea], bis(2-hydroxyethyl)ammonium acetate [bheaa], 2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium acetate [hhemea], 2-hydroxyethanaminium lactate [hel], bis(2-hydroxyethyl)ammonium lactate [bheal], 2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium lactate [hhemel] at temperatures (298.15, 313.15, and 328.16) K and pressures ranging from (100 to 1600) kPa was determined. From the experimental solubility data, the Henry’s constant of CO2 for each hydroxyl ammonium ionic liquids was estimated and reported as a function of temperature. Furthermore, enthalpy and entropy of absorption were obtained from estimated Henry’s constant. The results showed that the solubility increase with increasing pressure and decrease with increasing temperature and the solubility of CO2 in these six hydroxyl ammonium ionic liquids was in sequence: [hea] > [bheaa] > [hel] > [bheal] > [hhemel] > [hhemea]. Elsevier 2009 Citation Index Journal PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/717/1/www.sciencedirect.com_-jct.pdf Kurnia, Kiki and Murugesan, Thanapalan and M.I., Abdul Mutalib and Harris, F (2009) Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa. [Citation Index Journal] http://www.sciencedirect.com
spellingShingle QD Chemistry
Kurnia, Kiki
Murugesan, Thanapalan
M.I., Abdul Mutalib
Harris, F
Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa
title Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa
title_full Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa
title_fullStr Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa
title_full_unstemmed Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa
title_short Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa
title_sort thermodynamic properties of co2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kpa
topic QD Chemistry
url http://scholars.utp.edu.my/id/eprint/717/
http://scholars.utp.edu.my/id/eprint/717/
http://scholars.utp.edu.my/id/eprint/717/1/www.sciencedirect.com_-jct.pdf