Removal of chromium (VI) from aqueous solution using treated oil palm fibre

This study proposed an oil palm by-product as a low-cost adsorbent for the removal of hexavalent chromium [Cr (VI)] from aqueous solution. Adsorption of Cr (VI) by sulphuric acid and heat-treated oil palm fibre was conducted using batch tests. The influence of pH, contact time, initial chromium conc...

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Main Authors: M.H, Isa, N, Ibrahim, H.A, Aziz, Mohd.N, Adlan, N.H.Md, Sabiani, A.A.L, Zinatizadeh, S.R.M, Kutty
Format: Citation Index Journal
Language:English
Published: 2008
Subjects:
Online Access:http://scholars.utp.edu.my/id/eprint/6/
http://scholars.utp.edu.my/id/eprint/6/1/paper.pdf
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author M.H, Isa
N, Ibrahim
H.A, Aziz
Mohd.N, Adlan
N.H.Md, Sabiani
A.A.L, Zinatizadeh
S.R.M, Kutty
author_facet M.H, Isa
N, Ibrahim
H.A, Aziz
Mohd.N, Adlan
N.H.Md, Sabiani
A.A.L, Zinatizadeh
S.R.M, Kutty
author_sort M.H, Isa
building UTP Institutional Repository
collection Online Access
description This study proposed an oil palm by-product as a low-cost adsorbent for the removal of hexavalent chromium [Cr (VI)] from aqueous solution. Adsorption of Cr (VI) by sulphuric acid and heat-treated oil palm fibre was conducted using batch tests. The influence of pH, contact time, initial chromium concentration and adsorbent dosage on the removal of Cr (VI) from the solutions was investigated. The optimum initial pH for maximum uptake of Cr (VI) from aqueous solution was found to be 1.5. The removal efficiency was found to correlate with the initial Cr (VI) concentration, adsorbent dosage as well as the contact time between Cr (VI) and the adsorbent. The adsorption kinetics tested with pseudo first order and pseudo second order models yielded high R<sup>2</sup> values from 0.9254 to 0.9870 and from 0.9936 to 0.9998, respectively. The analysis of variance (ANOVA) showed significant difference between the R<sup>2</sup> values of the two models at 99% confidence level. The Freundlich isotherm (R<sup>2</sup> = 0.8778) described Cr (VI) adsorption slightly better than the Langmuir isotherm (R<sup>2</sup> = 0.8715). Difficulty in desorption of Cr (VI) suggests the suitability of treated oil palm fibre as a single-use adsorbent for Cr (VI) removal from aqueous solution. © 2007 Elsevier B.V. All rights reserved.
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institution Universiti Teknologi Petronas
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spelling oai:scholars.utp.edu.my:62017-01-19T08:26:34Z http://scholars.utp.edu.my/id/eprint/6/ Removal of chromium (VI) from aqueous solution using treated oil palm fibre M.H, Isa N, Ibrahim H.A, Aziz Mohd.N, Adlan N.H.Md, Sabiani A.A.L, Zinatizadeh S.R.M, Kutty TA Engineering (General). Civil engineering (General) This study proposed an oil palm by-product as a low-cost adsorbent for the removal of hexavalent chromium [Cr (VI)] from aqueous solution. Adsorption of Cr (VI) by sulphuric acid and heat-treated oil palm fibre was conducted using batch tests. The influence of pH, contact time, initial chromium concentration and adsorbent dosage on the removal of Cr (VI) from the solutions was investigated. The optimum initial pH for maximum uptake of Cr (VI) from aqueous solution was found to be 1.5. The removal efficiency was found to correlate with the initial Cr (VI) concentration, adsorbent dosage as well as the contact time between Cr (VI) and the adsorbent. The adsorption kinetics tested with pseudo first order and pseudo second order models yielded high R<sup>2</sup> values from 0.9254 to 0.9870 and from 0.9936 to 0.9998, respectively. The analysis of variance (ANOVA) showed significant difference between the R<sup>2</sup> values of the two models at 99% confidence level. The Freundlich isotherm (R<sup>2</sup> = 0.8778) described Cr (VI) adsorption slightly better than the Langmuir isotherm (R<sup>2</sup> = 0.8715). Difficulty in desorption of Cr (VI) suggests the suitability of treated oil palm fibre as a single-use adsorbent for Cr (VI) removal from aqueous solution. © 2007 Elsevier B.V. All rights reserved. 2008 Citation Index Journal PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/6/1/paper.pdf M.H, Isa and N, Ibrahim and H.A, Aziz and Mohd.N, Adlan and N.H.Md, Sabiani and A.A.L, Zinatizadeh and S.R.M, Kutty (2008) Removal of chromium (VI) from aqueous solution using treated oil palm fibre. [Citation Index Journal] 10.1016/j.jhazmat.2007.07.033 10.1016/j.jhazmat.2007.07.033 10.1016/j.jhazmat.2007.07.033
spellingShingle TA Engineering (General). Civil engineering (General)
M.H, Isa
N, Ibrahim
H.A, Aziz
Mohd.N, Adlan
N.H.Md, Sabiani
A.A.L, Zinatizadeh
S.R.M, Kutty
Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_full Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_fullStr Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_full_unstemmed Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_short Removal of chromium (VI) from aqueous solution using treated oil palm fibre
title_sort removal of chromium (vi) from aqueous solution using treated oil palm fibre
topic TA Engineering (General). Civil engineering (General)
url http://scholars.utp.edu.my/id/eprint/6/
http://scholars.utp.edu.my/id/eprint/6/
http://scholars.utp.edu.my/id/eprint/6/1/paper.pdf