Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K
In the present work, thermophysical properties such as density (ρ), dynamic viscosity (η), refractive index (nD), and surface tension (σ) of aqueous piperazine (PZ) solutions with mass fractions (100w = 1.74, 5.16, 10.35) have been measured from temperatures (298.15 to 338.15) K. All of these proper...
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| Format: | Citation Index Journal |
| Language: | English |
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2009
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| Online Access: | http://scholars.utp.edu.my/id/eprint/595/ http://scholars.utp.edu.my/id/eprint/595/1/paper.pdf |
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| author | A., Muhammad M.I.A., Mutalib T., Murugesan A., Shafeeq |
| author_facet | A., Muhammad M.I.A., Mutalib T., Murugesan A., Shafeeq |
| author_sort | A., Muhammad |
| building | UTP Institutional Repository |
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| description | In the present work, thermophysical properties such as density (ρ), dynamic viscosity (η), refractive index (nD), and surface tension (σ) of aqueous piperazine (PZ) solutions with mass fractions (100w = 1.74, 5.16, 10.35) have been measured from temperatures (298.15 to 338.15) K. All of these properties have also been measured for the aqueous blends of N-methyldiethanolamine (MDEA) and piperazine (PZ) with mass fractions {100(w1/w2)= 32.28/1.74, 32.28/5.16, 32.28/10.35, 48.80/1.74, 48.80/5.16, 48.80/10.35)} for the entire temperature range. The limit of PZ solubility in water was measured by the addition of a known quantity of anhydrous PZ (solid crystals) in 20 mL of distilled water at temperatures (278 to 343) K with a regular interval of 5 K. The experimental values of the studied physical properties have been compared with the literature and also correlated as a function of temperature. The coefficients of thermal expansion (αp) values have been calculated from their experimental density data using an empirical correlation. A thermogravimetric analyzer (TGA) has been used to explore the thermal stability of the studied solvent systems at a heating rate of 10 °C• min-1. © 2009 American Chemical Society.
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| first_indexed | 2025-11-13T07:23:43Z |
| format | Citation Index Journal |
| id | oai:scholars.utp.edu.my:595 |
| institution | Universiti Teknologi Petronas |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-13T07:23:43Z |
| publishDate | 2009 |
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| spelling | oai:scholars.utp.edu.my:5952023-01-04T02:25:02Z http://scholars.utp.edu.my/id/eprint/595/ Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K A., Muhammad M.I.A., Mutalib T., Murugesan A., Shafeeq TP Chemical technology In the present work, thermophysical properties such as density (ρ), dynamic viscosity (η), refractive index (nD), and surface tension (σ) of aqueous piperazine (PZ) solutions with mass fractions (100w = 1.74, 5.16, 10.35) have been measured from temperatures (298.15 to 338.15) K. All of these properties have also been measured for the aqueous blends of N-methyldiethanolamine (MDEA) and piperazine (PZ) with mass fractions {100(w1/w2)= 32.28/1.74, 32.28/5.16, 32.28/10.35, 48.80/1.74, 48.80/5.16, 48.80/10.35)} for the entire temperature range. The limit of PZ solubility in water was measured by the addition of a known quantity of anhydrous PZ (solid crystals) in 20 mL of distilled water at temperatures (278 to 343) K with a regular interval of 5 K. The experimental values of the studied physical properties have been compared with the literature and also correlated as a function of temperature. The coefficients of thermal expansion (αp) values have been calculated from their experimental density data using an empirical correlation. A thermogravimetric analyzer (TGA) has been used to explore the thermal stability of the studied solvent systems at a heating rate of 10 °C• min-1. © 2009 American Chemical Society. 2009 Citation Index Journal NonPeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/595/1/paper.pdf A., Muhammad and M.I.A., Mutalib and T., Murugesan and A., Shafeeq (2009) Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K. [Citation Index Journal] http://www.scopus.com/inward/record.url?eid=2-s2.0-69049112226&partnerID=40&md5=9a08782de91d7c1694113c7ff7511309 10.1021/je9000069 10.1021/je9000069 10.1021/je9000069 |
| spellingShingle | TP Chemical technology A., Muhammad M.I.A., Mutalib T., Murugesan A., Shafeeq Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K |
| title | Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K |
| title_full | Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K |
| title_fullStr | Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K |
| title_full_unstemmed | Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K |
| title_short | Thermophysical properties of aqueous piperazine and aqueous (N-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) K |
| title_sort | thermophysical properties of aqueous piperazine and aqueous (n-methyldiethanolamine + piperazine) solutions at temperatures (298.15 to 338.15) k |
| topic | TP Chemical technology |
| url | http://scholars.utp.edu.my/id/eprint/595/ http://scholars.utp.edu.my/id/eprint/595/ http://scholars.utp.edu.my/id/eprint/595/ http://scholars.utp.edu.my/id/eprint/595/1/paper.pdf |