Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents
Adsorption mechanism of a natural compound, alizarin (1,2-dihydroxyanthraquinone), onto three types of microporous polymeric adsorbents (XAD-4, XAD-7, XAD-16) has been proposed using Langmuir, Freundlich and Redlich-Petersen isotherms. Adsorption capacity and optimum adsorption isotherms were predic...
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| Format: | Citation Index Journal |
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2009
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| Online Access: | http://scholars.utp.edu.my/id/eprint/513/ http://scholars.utp.edu.my/id/eprint/513/1/ http://scholars.utp.edu.my/id/eprint/513/2/Comparative-evaluation-of-adsorption-kinetics-and-isotherms-of-a-natural-product-removal-by-Amberlite-polymeric-adsorbents_2009_Chemical-Engineering-Journal.pdf |
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| author | M.A., Abdullah L., Chiang M., Nadeem |
| author_facet | M.A., Abdullah L., Chiang M., Nadeem |
| author_sort | M.A., Abdullah |
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| description | Adsorption mechanism of a natural compound, alizarin (1,2-dihydroxyanthraquinone), onto three types of microporous polymeric adsorbents (XAD-4, XAD-7, XAD-16) has been proposed using Langmuir, Freundlich and Redlich-Petersen isotherms. Adsorption capacity and optimum adsorption isotherms were predicted by linear least squares and non-linear regression method. Adsorption kinetics was proposed by pseudo-first and second second order models. The adsorption capacity of XAD-16 was the highest at 0.0424 mg/mg, with initial alizarin concentration of 200 mg/L. Pseudo-second-order kinetics was more appropriate in explaining the adsorption mechanism than pseudo-first-order. Over the studied concentration ranges, only XAD-4 adsorption can be reasonably described by the three isotherms. XAD-16 data is only best-fitted to Langmuir and Redlich-Petersen isotherms. Non-linear method proved a better way to predict the equilibrium isotherm parameters. The combination of parameters, such as specific surface area, pore diameter, polarity of the network of the resins, the solubility and polarity of the adsorbate, are the significant parameters for optimum adsorption process. Crown Copyright © 2008.
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| first_indexed | 2025-11-13T07:23:30Z |
| format | Citation Index Journal |
| id | oai:scholars.utp.edu.my:513 |
| institution | Universiti Teknologi Petronas |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-13T07:23:30Z |
| publishDate | 2009 |
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| spelling | oai:scholars.utp.edu.my:5132017-01-19T08:25:47Z http://scholars.utp.edu.my/id/eprint/513/ Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents M.A., Abdullah L., Chiang M., Nadeem TP Chemical technology Adsorption mechanism of a natural compound, alizarin (1,2-dihydroxyanthraquinone), onto three types of microporous polymeric adsorbents (XAD-4, XAD-7, XAD-16) has been proposed using Langmuir, Freundlich and Redlich-Petersen isotherms. Adsorption capacity and optimum adsorption isotherms were predicted by linear least squares and non-linear regression method. Adsorption kinetics was proposed by pseudo-first and second second order models. The adsorption capacity of XAD-16 was the highest at 0.0424 mg/mg, with initial alizarin concentration of 200 mg/L. Pseudo-second-order kinetics was more appropriate in explaining the adsorption mechanism than pseudo-first-order. Over the studied concentration ranges, only XAD-4 adsorption can be reasonably described by the three isotherms. XAD-16 data is only best-fitted to Langmuir and Redlich-Petersen isotherms. Non-linear method proved a better way to predict the equilibrium isotherm parameters. The combination of parameters, such as specific surface area, pore diameter, polarity of the network of the resins, the solubility and polarity of the adsorbate, are the significant parameters for optimum adsorption process. Crown Copyright © 2008. 2009 Citation Index Journal PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/513/1/ application/pdf en http://scholars.utp.edu.my/id/eprint/513/2/Comparative-evaluation-of-adsorption-kinetics-and-isotherms-of-a-natural-product-removal-by-Amberlite-polymeric-adsorbents_2009_Chemical-Engineering-Journal.pdf M.A., Abdullah and L., Chiang and M., Nadeem (2009) Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents. [Citation Index Journal] http://www.scopus.com/inward/record.url?eid=2-s2.0-58349087399&partnerID=40&md5=f6f89c186726cbab0defe0b03cfb4775 10.1016/j.cej.2008.06.018 10.1016/j.cej.2008.06.018 10.1016/j.cej.2008.06.018 |
| spellingShingle | TP Chemical technology M.A., Abdullah L., Chiang M., Nadeem Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents |
| title | Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents
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| title_full | Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents
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| title_fullStr | Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents
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| title_full_unstemmed | Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents
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| title_short | Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents
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| title_sort | comparative evaluation of adsorption kinetics and isotherms of a natural product removal by amberlite polymeric adsorbents |
| topic | TP Chemical technology |
| url | http://scholars.utp.edu.my/id/eprint/513/ http://scholars.utp.edu.my/id/eprint/513/ http://scholars.utp.edu.my/id/eprint/513/ http://scholars.utp.edu.my/id/eprint/513/1/ http://scholars.utp.edu.my/id/eprint/513/2/Comparative-evaluation-of-adsorption-kinetics-and-isotherms-of-a-natural-product-removal-by-Amberlite-polymeric-adsorbents_2009_Chemical-Engineering-Journal.pdf |