Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process

The study examined the effect of operating conditions (zinc oxide concentration, pH and irradiation time) of the UV/ZnO photocatalytic process on degradation of amoxicillin, ampicillin and cloxacillin in aqueous solution. pH has a great effect on amoxicillin, ampicillin and cloxacillin degradation....

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Main Authors: Chaudhuri, M., E.S., Elmolla
Format: Citation Index Journal
Language:English
Published: 2010
Subjects:
Online Access:http://scholars.utp.edu.my/id/eprint/34/
http://scholars.utp.edu.my/id/eprint/34/1/paper.pdf
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author Chaudhuri, M.
E.S., Elmolla
author_facet Chaudhuri, M.
E.S., Elmolla
author_sort Chaudhuri, M.
building UTP Institutional Repository
collection Online Access
description The study examined the effect of operating conditions (zinc oxide concentration, pH and irradiation time) of the UV/ZnO photocatalytic process on degradation of amoxicillin, ampicillin and cloxacillin in aqueous solution. pH has a great effect on amoxicillin, ampicillin and cloxacillin degradation. The optimum operating conditions for complete degradation of antibiotics in an aqueous solution containing 104, 105 and 103 mg/L amoxicillin, ampicillin and cloxacillin, respectively were: zinc oxide 0.5 g/L, irradiation time 180 min and pH 11. Under optimum operating conditions, complete degradation of amoxicillin, ampicillin and cloxacillin occurred and COD and DOC removal were 23.9 and 9.7%, respectively. The photocatalytic reactions under optimum conditions approximately followed a pseudo-first order kinetics with rate constant (k) 0.018, 0.015 and 0.029 min -1 for amoxicillin, ampicillin and cloxacillin, respectively. UV/ZnO photocatalysis can be used for amoxicillin, ampicillin and cloxacillin degradation in aqueous solution. © 2009 Elsevier B.V. All rights reserved.
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spelling oai:scholars.utp.edu.my:342017-01-19T08:24:37Z http://scholars.utp.edu.my/id/eprint/34/ Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process Chaudhuri, M. E.S., Elmolla TA Engineering (General). Civil engineering (General) The study examined the effect of operating conditions (zinc oxide concentration, pH and irradiation time) of the UV/ZnO photocatalytic process on degradation of amoxicillin, ampicillin and cloxacillin in aqueous solution. pH has a great effect on amoxicillin, ampicillin and cloxacillin degradation. The optimum operating conditions for complete degradation of antibiotics in an aqueous solution containing 104, 105 and 103 mg/L amoxicillin, ampicillin and cloxacillin, respectively were: zinc oxide 0.5 g/L, irradiation time 180 min and pH 11. Under optimum operating conditions, complete degradation of amoxicillin, ampicillin and cloxacillin occurred and COD and DOC removal were 23.9 and 9.7%, respectively. The photocatalytic reactions under optimum conditions approximately followed a pseudo-first order kinetics with rate constant (k) 0.018, 0.015 and 0.029 min -1 for amoxicillin, ampicillin and cloxacillin, respectively. UV/ZnO photocatalysis can be used for amoxicillin, ampicillin and cloxacillin degradation in aqueous solution. © 2009 Elsevier B.V. All rights reserved. 2010 Citation Index Journal PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/34/1/paper.pdf Chaudhuri, M. and E.S., Elmolla (2010) Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process. [Citation Index Journal] 10.1016/j.jhazmat.2009.08.104 10.1016/j.jhazmat.2009.08.104 10.1016/j.jhazmat.2009.08.104
spellingShingle TA Engineering (General). Civil engineering (General)
Chaudhuri, M.
E.S., Elmolla
Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process
title Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process
title_full Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process
title_fullStr Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process
title_full_unstemmed Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process
title_short Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process
title_sort degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the uv/zno photocatalytic process
topic TA Engineering (General). Civil engineering (General)
url http://scholars.utp.edu.my/id/eprint/34/
http://scholars.utp.edu.my/id/eprint/34/
http://scholars.utp.edu.my/id/eprint/34/1/paper.pdf