Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite

Unsaturated polyester resin, synthesized from glycolyzed product of poly (ethylene terephthalate) (PET) waste was combined with rice husks to form rice husk (RH)/polyester composites. PET from post-consumer soft drink bottles was recycled through glycolysis, followed by polyesterified with maleic a...

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Main Authors: Ahmad, Ishak, Abu Bakar, Dayang Ratnasari, Mokhilas, Siti Noradilah, Ramli, Anita
Format: Citation Index Journal
Language:English
Published: 2007
Subjects:
Online Access:http://scholars.utp.edu.my/id/eprint/3287/
http://scholars.utp.edu.my/id/eprint/3287/1/IPJ-2007-07-2130_Ishak%26Anita.pdf
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author Ahmad, Ishak
Abu Bakar, Dayang Ratnasari
Mokhilas, Siti Noradilah
Ramli, Anita
author_facet Ahmad, Ishak
Abu Bakar, Dayang Ratnasari
Mokhilas, Siti Noradilah
Ramli, Anita
author_sort Ahmad, Ishak
building UTP Institutional Repository
collection Online Access
description Unsaturated polyester resin, synthesized from glycolyzed product of poly (ethylene terephthalate) (PET) waste was combined with rice husks to form rice husk (RH)/polyester composites. PET from post-consumer soft drink bottles was recycled through glycolysis, followed by polyesterified with maleic anhydride and then cross-linked with styrene to produce a formulation for the resin. Characterizations of the synthesized resin were performed by hydroxyl and acid values determinations and Fourier transform infra red (FTIR) technique. The FTIR result for the prepared resin showed that cross-linking between polyester chain and styrene as cross-linkable monomer occurred at their unsaturated active sites. The effects of filler loading and surface modification of rice husks on the mechanical properties and water absorption of the composites were also investigated. It has been observed that the increasing filler loading resulted in reduction of tensile strength, elongation-at-break and impact energy but increased tensile modulus, hardness and water absorption. At similar filler loading, alkalized filler composite has higher mechanical properties. This observation was well supported by the SEM investigations of the fracture surfaces.
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format Citation Index Journal
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institution Universiti Teknologi Petronas
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language English
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spelling oai:scholars.utp.edu.my:32872017-01-19T08:27:00Z http://scholars.utp.edu.my/id/eprint/3287/ Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite Ahmad, Ishak Abu Bakar, Dayang Ratnasari Mokhilas, Siti Noradilah Ramli, Anita TP Chemical technology QD Chemistry Unsaturated polyester resin, synthesized from glycolyzed product of poly (ethylene terephthalate) (PET) waste was combined with rice husks to form rice husk (RH)/polyester composites. PET from post-consumer soft drink bottles was recycled through glycolysis, followed by polyesterified with maleic anhydride and then cross-linked with styrene to produce a formulation for the resin. Characterizations of the synthesized resin were performed by hydroxyl and acid values determinations and Fourier transform infra red (FTIR) technique. The FTIR result for the prepared resin showed that cross-linking between polyester chain and styrene as cross-linkable monomer occurred at their unsaturated active sites. The effects of filler loading and surface modification of rice husks on the mechanical properties and water absorption of the composites were also investigated. It has been observed that the increasing filler loading resulted in reduction of tensile strength, elongation-at-break and impact energy but increased tensile modulus, hardness and water absorption. At similar filler loading, alkalized filler composite has higher mechanical properties. This observation was well supported by the SEM investigations of the fracture surfaces. 2007 Citation Index Journal PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/3287/1/IPJ-2007-07-2130_Ishak%26Anita.pdf Ahmad, Ishak and Abu Bakar, Dayang Ratnasari and Mokhilas, Siti Noradilah and Ramli, Anita (2007) Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite. [Citation Index Journal]
spellingShingle TP Chemical technology
QD Chemistry
Ahmad, Ishak
Abu Bakar, Dayang Ratnasari
Mokhilas, Siti Noradilah
Ramli, Anita
Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite
title Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite
title_full Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite
title_fullStr Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite
title_full_unstemmed Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite
title_short Direct Usage of Products of Poly(ethylene terephthalate) Glycolysis for Manufacturing of Rice Husk/Unsaturated Polyester Composite
title_sort direct usage of products of poly(ethylene terephthalate) glycolysis for manufacturing of rice husk/unsaturated polyester composite
topic TP Chemical technology
QD Chemistry
url http://scholars.utp.edu.my/id/eprint/3287/
http://scholars.utp.edu.my/id/eprint/3287/1/IPJ-2007-07-2130_Ishak%26Anita.pdf