Prediction of the thermal conductivity of metal hydrides - The inverse problem

With sustainability as an important and driving theme, not merely of research, but that of our existence itself, the effort in developing sustainable systems takes many directions. One of these directions is in the transport sector, particularly personal transport using hydrogen as fuel, which logic...

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Main Authors: Mohd Fahmi Abdul, Ghafir, Mohd Faizal Mohideen, Batcha, Vijay R., Raghavan
Format: Conference or Workshop Item
Language:English
Published: 2009
Subjects:
Online Access:http://scholars.utp.edu.my/id/eprint/2342/
http://scholars.utp.edu.my/id/eprint/2342/1/SAMPLE_PAPER_PDF.pdf
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author Mohd Fahmi Abdul, Ghafir
Mohd Faizal Mohideen, Batcha
Vijay R., Raghavan
author_facet Mohd Fahmi Abdul, Ghafir
Mohd Faizal Mohideen, Batcha
Vijay R., Raghavan
author_sort Mohd Fahmi Abdul, Ghafir
building UTP Institutional Repository
collection Online Access
description With sustainability as an important and driving theme, not merely of research, but that of our existence itself, the effort in developing sustainable systems takes many directions. One of these directions is in the transport sector, particularly personal transport using hydrogen as fuel, which logically leads on to the problem of hydrogen storage. This paper deals with the prediction of the effective conductivity of beds of metal hydride for hydrogen storage. To enable modeling of the effective thermal conductivity of these systems, it is necessary to arrive at the functional dependence of the thermal conductivity of the solid hydride on its hydrogen concentration or content. This is the inverse problem in thermal conductivity of multiphase materials. Inverse methods in general are those where we start from known consequences in order to find unknown causes. Using published and known data of the effective thermal conductivity of the hydride-hydrogen assemblage, we arrive at the unknown hydride conductivity by analysis. Among the models available in the literature for determination of the effective conductivity of the bed from the properties of the constituent phases, the model of Raghavan and Martin is chosen for the analysis as it combines simplicity and physical rigor. The result is expected to be useful for predicting the thermal conductivity of hydride particles and determining the optimum heat transfer rates governing the absorption and desorption rates of hydrogen in the storage system. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
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institution Universiti Teknologi Petronas
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spelling oai:scholars.utp.edu.my:23422017-01-19T08:25:17Z http://scholars.utp.edu.my/id/eprint/2342/ Prediction of the thermal conductivity of metal hydrides - The inverse problem Mohd Fahmi Abdul, Ghafir Mohd Faizal Mohideen, Batcha Vijay R., Raghavan TP Chemical technology With sustainability as an important and driving theme, not merely of research, but that of our existence itself, the effort in developing sustainable systems takes many directions. One of these directions is in the transport sector, particularly personal transport using hydrogen as fuel, which logically leads on to the problem of hydrogen storage. This paper deals with the prediction of the effective conductivity of beds of metal hydride for hydrogen storage. To enable modeling of the effective thermal conductivity of these systems, it is necessary to arrive at the functional dependence of the thermal conductivity of the solid hydride on its hydrogen concentration or content. This is the inverse problem in thermal conductivity of multiphase materials. Inverse methods in general are those where we start from known consequences in order to find unknown causes. Using published and known data of the effective thermal conductivity of the hydride-hydrogen assemblage, we arrive at the unknown hydride conductivity by analysis. Among the models available in the literature for determination of the effective conductivity of the bed from the properties of the constituent phases, the model of Raghavan and Martin is chosen for the analysis as it combines simplicity and physical rigor. The result is expected to be useful for predicting the thermal conductivity of hydride particles and determining the optimum heat transfer rates governing the absorption and desorption rates of hydrogen in the storage system. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved. 2009-08 Conference or Workshop Item PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/2342/1/SAMPLE_PAPER_PDF.pdf Mohd Fahmi Abdul, Ghafir and Mohd Faizal Mohideen, Batcha and Vijay R., Raghavan (2009) Prediction of the thermal conductivity of metal hydrides - The inverse problem. In: 4th Dubrovnik Conference on Sustainable Development of Energy, Water and Environment Systems, APR, 2007 , Dubrovnik, CROATIA. http://apps.isiknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=12&SID=X212JDdPAc7358p5C3D&page=1&doc=1
spellingShingle TP Chemical technology
Mohd Fahmi Abdul, Ghafir
Mohd Faizal Mohideen, Batcha
Vijay R., Raghavan
Prediction of the thermal conductivity of metal hydrides - The inverse problem
title Prediction of the thermal conductivity of metal hydrides - The inverse problem
title_full Prediction of the thermal conductivity of metal hydrides - The inverse problem
title_fullStr Prediction of the thermal conductivity of metal hydrides - The inverse problem
title_full_unstemmed Prediction of the thermal conductivity of metal hydrides - The inverse problem
title_short Prediction of the thermal conductivity of metal hydrides - The inverse problem
title_sort prediction of the thermal conductivity of metal hydrides - the inverse problem
topic TP Chemical technology
url http://scholars.utp.edu.my/id/eprint/2342/
http://scholars.utp.edu.my/id/eprint/2342/
http://scholars.utp.edu.my/id/eprint/2342/1/SAMPLE_PAPER_PDF.pdf