Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study

Discharging of excessive wastewater nutrient in the form of ammoniacal nitrogen (N-NH4) into the receiving water causes environmental problems such as eutrophication, corrosion and fouling. Presently N-NH4 is removed from wastewater in tertiary treatment. The purpose of the present study was to inve...

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Main Authors: Aziz, H.A., Hussain, S., Isa, M.H., Asaari, F.A.H., Adlan, M.N.
Format: Conference or Workshop Item
Language:English
Published: 2005
Subjects:
Online Access:http://scholars.utp.edu.my/id/eprint/1434/
http://scholars.utp.edu.my/id/eprint/1434/1/Ammoniacal_Nitrogen_Removal_from_Synthetic_Wastewater_Using_Limestone_and_Granular_Activated_Carbon_in_Batch_Study.pdf
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author Aziz, H.A.
Hussain, S.
Isa, M.H.
Asaari, F.A.H.
Adlan, M.N.
author_facet Aziz, H.A.
Hussain, S.
Isa, M.H.
Asaari, F.A.H.
Adlan, M.N.
author_sort Aziz, H.A.
building UTP Institutional Repository
collection Online Access
description Discharging of excessive wastewater nutrient in the form of ammoniacal nitrogen (N-NH4) into the receiving water causes environmental problems such as eutrophication, corrosion and fouling. Presently N-NH4 is removed from wastewater in tertiary treatment. The purpose of the present study was to investigate the removal of N-NH4 from synthetic wastewater using limestone (LS) as low cost media and granular activated carbon (GAC). The physio-chemical treatment adopted in this study is preferred over the other methods because of its simplicity, easy maintenance and quality control. The batch experiments were investigated to evaluate the combine mixture ratio of limestone and activated carbon at pre-examined optimum conditions on the removal of both parameters. Results indicated that 58% of N-NH4 was successfully removed at optimum media ratio of 25:15 (LS:GAC). Results indicated that the smaller particle size of media was more effective than larger particle size because small size particle causes a higher adsorption capacity due to great available surface area. The equilibrium adsorption data is fit and followed Freundlich isotherm (Kf=1875, n=0.42 and R2=0.9827). The experimental data agreed with the pseudo second-order kinetic model (R2 > 0.90). This shows that the usage of GAC can be reduced by combining the media with limestone. The study indicated the potential use of LS and GAC for the treatment of N-NH4 and P-PO4 from wastewater at lower cost as compared to the use of GAC alone.
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spelling oai:scholars.utp.edu.my:14342017-01-19T08:27:27Z http://scholars.utp.edu.my/id/eprint/1434/ Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study Aziz, H.A. Hussain, S. Isa, M.H. Asaari, F.A.H. Adlan, M.N. TD Environmental technology. Sanitary engineering Discharging of excessive wastewater nutrient in the form of ammoniacal nitrogen (N-NH4) into the receiving water causes environmental problems such as eutrophication, corrosion and fouling. Presently N-NH4 is removed from wastewater in tertiary treatment. The purpose of the present study was to investigate the removal of N-NH4 from synthetic wastewater using limestone (LS) as low cost media and granular activated carbon (GAC). The physio-chemical treatment adopted in this study is preferred over the other methods because of its simplicity, easy maintenance and quality control. The batch experiments were investigated to evaluate the combine mixture ratio of limestone and activated carbon at pre-examined optimum conditions on the removal of both parameters. Results indicated that 58% of N-NH4 was successfully removed at optimum media ratio of 25:15 (LS:GAC). Results indicated that the smaller particle size of media was more effective than larger particle size because small size particle causes a higher adsorption capacity due to great available surface area. The equilibrium adsorption data is fit and followed Freundlich isotherm (Kf=1875, n=0.42 and R2=0.9827). The experimental data agreed with the pseudo second-order kinetic model (R2 > 0.90). This shows that the usage of GAC can be reduced by combining the media with limestone. The study indicated the potential use of LS and GAC for the treatment of N-NH4 and P-PO4 from wastewater at lower cost as compared to the use of GAC alone. 2005-11 Conference or Workshop Item PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/1434/1/Ammoniacal_Nitrogen_Removal_from_Synthetic_Wastewater_Using_Limestone_and_Granular_Activated_Carbon_in_Batch_Study.pdf Aziz, H.A. and Hussain, S. and Isa, M.H. and Asaari, F.A.H. and Adlan, M.N. (2005) Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study. In: International Conference on Natural Resources and Environmental Management (NREM 2005), Institut Kimia Malaysia, Kuching, Sarawak, Malaysia, November, 2005, Kuching, Sarawak, Malaysia.
spellingShingle TD Environmental technology. Sanitary engineering
Aziz, H.A.
Hussain, S.
Isa, M.H.
Asaari, F.A.H.
Adlan, M.N.
Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study
title Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study
title_full Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study
title_fullStr Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study
title_full_unstemmed Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study
title_short Ammoniacal Nitrogen Removal from Synthetic Wastewater Using Limestone and Granular Activated Carbon in Batch Study
title_sort ammoniacal nitrogen removal from synthetic wastewater using limestone and granular activated carbon in batch study
topic TD Environmental technology. Sanitary engineering
url http://scholars.utp.edu.my/id/eprint/1434/
http://scholars.utp.edu.my/id/eprint/1434/1/Ammoniacal_Nitrogen_Removal_from_Synthetic_Wastewater_Using_Limestone_and_Granular_Activated_Carbon_in_Batch_Study.pdf