Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran

Hydrate - aqueous liquid - vapor equilibrium conditions of clathrate hydrate formed from mixtures of carbon dioxide and hydrogen in aqueous tetrahydrofuran solutions (5.6 mol%) at different mixing ratios of CO2 and H2 are presented. All the phase equilibrium measurements are performed by using a C...

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Main Authors: K.M., Sabil, Nadia , Oujamma, Witkamp, Geert-Jan, Peters, Cor J., Bruining, Johannes M
Format: Conference or Workshop Item
Language:English
Published: 2010
Subjects:
Online Access:http://scholars.utp.edu.my/id/eprint/1402/
http://scholars.utp.edu.my/id/eprint/1402/1/Khalik_CCEA2010.pdf
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author K.M., Sabil
Nadia , Oujamma
Witkamp, Geert-Jan
Peters, Cor J.
Bruining, Johannes M
author_facet K.M., Sabil
Nadia , Oujamma
Witkamp, Geert-Jan
Peters, Cor J.
Bruining, Johannes M
author_sort K.M., Sabil
building UTP Institutional Repository
collection Online Access
description Hydrate - aqueous liquid - vapor equilibrium conditions of clathrate hydrate formed from mixtures of carbon dioxide and hydrogen in aqueous tetrahydrofuran solutions (5.6 mol%) at different mixing ratios of CO2 and H2 are presented. All the phase equilibrium measurements are performed by using a Cailletet apparatus. The experimental temperature range is from 275 up to 295 K and the pressure range is from 1 up to 10 MPa. The addition of THF has been proven to significantly reduce the hydrate equilibrium pressure at a specified temperature. Moreover, the hydrate formed in the aqueous THF solutions is found to be more thermally stable compared to that of in water only. Also, the equilibrium conditions are dependent on the ratio of CO2 and H2 in the mixture.
first_indexed 2025-11-13T07:25:19Z
format Conference or Workshop Item
id oai:scholars.utp.edu.my:1402
institution Universiti Teknologi Petronas
institution_category Local University
language English
last_indexed 2025-11-13T07:25:19Z
publishDate 2010
recordtype eprints
repository_type Digital Repository
spelling oai:scholars.utp.edu.my:14022017-03-20T07:13:17Z http://scholars.utp.edu.my/id/eprint/1402/ Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran K.M., Sabil Nadia , Oujamma Witkamp, Geert-Jan Peters, Cor J. Bruining, Johannes M TP Chemical technology Hydrate - aqueous liquid - vapor equilibrium conditions of clathrate hydrate formed from mixtures of carbon dioxide and hydrogen in aqueous tetrahydrofuran solutions (5.6 mol%) at different mixing ratios of CO2 and H2 are presented. All the phase equilibrium measurements are performed by using a Cailletet apparatus. The experimental temperature range is from 275 up to 295 K and the pressure range is from 1 up to 10 MPa. The addition of THF has been proven to significantly reduce the hydrate equilibrium pressure at a specified temperature. Moreover, the hydrate formed in the aqueous THF solutions is found to be more thermally stable compared to that of in water only. Also, the equilibrium conditions are dependent on the ratio of CO2 and H2 in the mixture. 2010-02-26 Conference or Workshop Item PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/1402/1/Khalik_CCEA2010.pdf K.M., Sabil and Nadia , Oujamma and Witkamp, Geert-Jan and Peters, Cor J. and Bruining, Johannes M (2010) Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran. In: the 2010 International Conference on Chemical Engineering and Applications, 26-28 February 2010, Singapore. http://www.iacsit.org/caas/Full%20version.pdf
spellingShingle TP Chemical technology
K.M., Sabil
Nadia , Oujamma
Witkamp, Geert-Jan
Peters, Cor J.
Bruining, Johannes M
Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran
title Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran
title_full Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran
title_fullStr Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran
title_full_unstemmed Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran
title_short Hydrate-Aqueous Liquid-Vapor Equilibrium (H-LW-V) for binary CO2/H2 Mixture in Aqueous Solutions of Water and Tetrahydrofuran
title_sort hydrate-aqueous liquid-vapor equilibrium (h-lw-v) for binary co2/h2 mixture in aqueous solutions of water and tetrahydrofuran
topic TP Chemical technology
url http://scholars.utp.edu.my/id/eprint/1402/
http://scholars.utp.edu.my/id/eprint/1402/
http://scholars.utp.edu.my/id/eprint/1402/1/Khalik_CCEA2010.pdf