Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System

The bubble- and dew- point behavior of the carbon dioxide (1) + tetrahydrofuran (2) + water (3) system has been studied. Pressure-temperature isopleths were measured for the ternary system at x1 ) 0.01, 0.02, 0.03, 0.04, 0.09, and 0.27 at a constant mole fraction of tetrahydrofuran, x2 ) 0.05. The...

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Main Authors: Sabil, Khalik M, Witkamp, Geert-Jan, Peters, Cor J.
Format: Citation Index Journal
Language:English
Published: ACS 2009
Subjects:
Online Access:http://scholars.utp.edu.my/id/eprint/1380/
http://scholars.utp.edu.my/id/eprint/1380/3/JEngData1.pdf
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author Sabil, Khalik M
Witkamp, Geert-Jan
Peters, Cor J.
author_facet Sabil, Khalik M
Witkamp, Geert-Jan
Peters, Cor J.
author_sort Sabil, Khalik M
building UTP Institutional Repository
collection Online Access
description The bubble- and dew- point behavior of the carbon dioxide (1) + tetrahydrofuran (2) + water (3) system has been studied. Pressure-temperature isopleths were measured for the ternary system at x1 ) 0.01, 0.02, 0.03, 0.04, 0.09, and 0.27 at a constant mole fraction of tetrahydrofuran, x2 ) 0.05. The bubble- and dewpoint lines for the ternary systems were also measured at x2 ) 0.01, 0.03, 0.05, and 0.07 for fixed composition of carbon dioxide (x1) at 0.04 mol fraction and at x2 ) 0.01, 0.03, 0.05, 0.06, and 0.09 for a fixed composition of carbon dioxide (x1) at 0.09, respectively. The pressure and temperature range from (1 to 6) MPa and (280 to 300) K, respectively. The experimental results for the ternary system have been modeled using the predictive Peng-Robinson-Stryjek-Vera (PRSV) equation of state with the Huron-Vidal-Orbey-Sandler (HVOS) mixing rule and the universal quasi-chemical activity coefficient (UNIQUAC) GE model. Excellent agreements have been found between the experimental and the predicted values of the bubble and dew points of the ternary system throughout the composition range studied.
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spelling oai:scholars.utp.edu.my:13802017-03-20T01:56:56Z http://scholars.utp.edu.my/id/eprint/1380/ Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System Sabil, Khalik M Witkamp, Geert-Jan Peters, Cor J. TP Chemical technology The bubble- and dew- point behavior of the carbon dioxide (1) + tetrahydrofuran (2) + water (3) system has been studied. Pressure-temperature isopleths were measured for the ternary system at x1 ) 0.01, 0.02, 0.03, 0.04, 0.09, and 0.27 at a constant mole fraction of tetrahydrofuran, x2 ) 0.05. The bubble- and dewpoint lines for the ternary systems were also measured at x2 ) 0.01, 0.03, 0.05, and 0.07 for fixed composition of carbon dioxide (x1) at 0.04 mol fraction and at x2 ) 0.01, 0.03, 0.05, 0.06, and 0.09 for a fixed composition of carbon dioxide (x1) at 0.09, respectively. The pressure and temperature range from (1 to 6) MPa and (280 to 300) K, respectively. The experimental results for the ternary system have been modeled using the predictive Peng-Robinson-Stryjek-Vera (PRSV) equation of state with the Huron-Vidal-Orbey-Sandler (HVOS) mixing rule and the universal quasi-chemical activity coefficient (UNIQUAC) GE model. Excellent agreements have been found between the experimental and the predicted values of the bubble and dew points of the ternary system throughout the composition range studied. ACS 2009-09 Citation Index Journal PeerReviewed application/pdf en http://scholars.utp.edu.my/id/eprint/1380/3/JEngData1.pdf Sabil, Khalik M and Witkamp, Geert-Jan and Peters, Cor J. (2009) Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System. [Citation Index Journal] http://pubs.acs.org/journal/jceaax
spellingShingle TP Chemical technology
Sabil, Khalik M
Witkamp, Geert-Jan
Peters, Cor J.
Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System
title Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System
title_full Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System
title_fullStr Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System
title_full_unstemmed Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System
title_short Measurement and Modeling of Bubble and Dew Points of the Carbon Dioxide + Tetrahydrofuran + Water System
title_sort measurement and modeling of bubble and dew points of the carbon dioxide + tetrahydrofuran + water system
topic TP Chemical technology
url http://scholars.utp.edu.my/id/eprint/1380/
http://scholars.utp.edu.my/id/eprint/1380/
http://scholars.utp.edu.my/id/eprint/1380/3/JEngData1.pdf