Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics

The effect of rare earth nanoparticles, M=Sm2O3, Nd2O3 and Ho2O3 added to (Bi1.6Pb0.4Sr2Ca2Cu3O10+δ)1-x(M)x, where x = 0.00 - 0.05, superconductor were studied by X-ray diffraction technique (XRD), resistivity (R), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDX). The volu...

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Main Authors: H. Baqiah, S.A. Halim, Chen, S.K., Lim, K.P., M.M. Awang Kechik
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2016
Online Access:http://journalarticle.ukm.my/9756/
http://journalarticle.ukm.my/9756/1/19_H._Bagiah.pdf
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author H. Baqiah,
S.A. Halim,
Chen, S.K.
Lim, K.P.
M.M. Awang Kechik,
author_facet H. Baqiah,
S.A. Halim,
Chen, S.K.
Lim, K.P.
M.M. Awang Kechik,
author_sort H. Baqiah,
building UKM Institutional Repository
collection Online Access
description The effect of rare earth nanoparticles, M=Sm2O3, Nd2O3 and Ho2O3 added to (Bi1.6Pb0.4Sr2Ca2Cu3O10+δ)1-x(M)x, where x = 0.00 - 0.05, superconductor were studied by X-ray diffraction technique (XRD), resistivity (R), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDX). The volume fraction of high-Tc phase, Bi-2223, decreased from 84% for pure sample to 48, 30 and 23% at x = 0.05 for Sm2O3, Ho2O3 and Nd2O3 additions, respectively. The critical temperature Tc(R=0) that is 102 K for the pure sample decreased to 78, 73 and 69 K at x = 0.05 for samples with Sm2O3, Nd2O3 and Ho2O3 nanoparticles additions, respectively. The additions of rare earth nanoparticles decreased the grain size and increased the random orientation of the grains. The results showed that the phases’ formations, variations of lattice parameters and electrical properties are sensitive to the size of nanoparticles and magnetic properties of its ions.
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spelling oai:generic.eprints.org:97562016-12-14T06:50:45Z http://journalarticle.ukm.my/9756/ Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics H. Baqiah, S.A. Halim, Chen, S.K. Lim, K.P. M.M. Awang Kechik, The effect of rare earth nanoparticles, M=Sm2O3, Nd2O3 and Ho2O3 added to (Bi1.6Pb0.4Sr2Ca2Cu3O10+δ)1-x(M)x, where x = 0.00 - 0.05, superconductor were studied by X-ray diffraction technique (XRD), resistivity (R), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDX). The volume fraction of high-Tc phase, Bi-2223, decreased from 84% for pure sample to 48, 30 and 23% at x = 0.05 for Sm2O3, Ho2O3 and Nd2O3 additions, respectively. The critical temperature Tc(R=0) that is 102 K for the pure sample decreased to 78, 73 and 69 K at x = 0.05 for samples with Sm2O3, Nd2O3 and Ho2O3 nanoparticles additions, respectively. The additions of rare earth nanoparticles decreased the grain size and increased the random orientation of the grains. The results showed that the phases’ formations, variations of lattice parameters and electrical properties are sensitive to the size of nanoparticles and magnetic properties of its ions. Penerbit Universiti Kebangsaan Malaysia 2016-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/9756/1/19_H._Bagiah.pdf H. Baqiah, and S.A. Halim, and Chen, S.K. and Lim, K.P. and M.M. Awang Kechik, (2016) Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics. Sains Malaysiana, 45 (4). pp. 643-651. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid45bil4_2016/KandunganJilid45Bil4_2016.htm
spellingShingle H. Baqiah,
S.A. Halim,
Chen, S.K.
Lim, K.P.
M.M. Awang Kechik,
Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_full Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_fullStr Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_full_unstemmed Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_short Effects of rare earth nanoparticles (M = Sm2O3, Ho2O3, Nd2O3) addition on the microstructure and superconducting transition of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics
title_sort effects of rare earth nanoparticles (m = sm2o3, ho2o3, nd2o3) addition on the microstructure and superconducting transition of bi1.6pb0.4sr2ca2cu3o10+δ ceramics
url http://journalarticle.ukm.my/9756/
http://journalarticle.ukm.my/9756/
http://journalarticle.ukm.my/9756/1/19_H._Bagiah.pdf