Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol

Glycerol is a valuable co-product from oleochemical industry such as from fatty acid and biodiesel production. By having three hydroxyl groups in its molecule, glycerol can undergo chemical modifications that lead to many possible applications. This paper reports the tosylation process of glycerol w...

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Main Authors: Yusrabbil Amiyati Yusof, Azhar Ariffin A.
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2016
Online Access:http://journalarticle.ukm.my/9753/
http://journalarticle.ukm.my/9753/1/16_Yusrabbil_Amiyati_Yusof.pdf
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author Yusrabbil Amiyati Yusof,
Azhar Ariffin A.,
author_facet Yusrabbil Amiyati Yusof,
Azhar Ariffin A.,
author_sort Yusrabbil Amiyati Yusof,
building UKM Institutional Repository
collection Online Access
description Glycerol is a valuable co-product from oleochemical industry such as from fatty acid and biodiesel production. By having three hydroxyl groups in its molecule, glycerol can undergo chemical modifications that lead to many possible applications. This paper reports the tosylation process of glycerol with para-toluenesulfonyl chloride (p-TsCl). Reaction of glycerol with p-TsCl in the presence of a base produced mono-, di- and tri-tosylate of glycerol even though the reaction was carried out at the mole ratio of 1.2:1.0 of glycerol to p-TsCl. The compounds were successfully isolated and characterized. Mono-, di- and tri-tosylate of glycerol exhibited inhibitory activity against Staphylococcus aureus (gram positive bacteria) and Pseudomonas aeruginosa (gram negative bacteria).
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spelling oai:generic.eprints.org:97532016-12-14T06:50:44Z http://journalarticle.ukm.my/9753/ Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol Yusrabbil Amiyati Yusof, Azhar Ariffin A., Glycerol is a valuable co-product from oleochemical industry such as from fatty acid and biodiesel production. By having three hydroxyl groups in its molecule, glycerol can undergo chemical modifications that lead to many possible applications. This paper reports the tosylation process of glycerol with para-toluenesulfonyl chloride (p-TsCl). Reaction of glycerol with p-TsCl in the presence of a base produced mono-, di- and tri-tosylate of glycerol even though the reaction was carried out at the mole ratio of 1.2:1.0 of glycerol to p-TsCl. The compounds were successfully isolated and characterized. Mono-, di- and tri-tosylate of glycerol exhibited inhibitory activity against Staphylococcus aureus (gram positive bacteria) and Pseudomonas aeruginosa (gram negative bacteria). Penerbit Universiti Kebangsaan Malaysia 2016-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/9753/1/16_Yusrabbil_Amiyati_Yusof.pdf Yusrabbil Amiyati Yusof, and Azhar Ariffin A., (2016) Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol. Sains Malaysiana, 45 (4). pp. 621-625. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid45bil4_2016/KandunganJilid45Bil4_2016.htm
spellingShingle Yusrabbil Amiyati Yusof,
Azhar Ariffin A.,
Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol
title Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol
title_full Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol
title_fullStr Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol
title_full_unstemmed Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol
title_short Synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol
title_sort synthesis, characterization and antibacterial activity of mono-, di- and tri-tosylate of glycerol
url http://journalarticle.ukm.my/9753/
http://journalarticle.ukm.my/9753/
http://journalarticle.ukm.my/9753/1/16_Yusrabbil_Amiyati_Yusof.pdf