Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites

Poly(butylene succinate) (PBS) composites with 30 wt.% loading of kenaf bast fibre (KBF) were compatibilised with 5 wt.% maleated PBS (PBS-g-MA). The maleic anhydride (MA) concentration in the compatibiliser was either 3, 5, 7 or 10 phr. In general, the compatibilised composites showed better flexur...

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Main Authors: Ahmad Thirmizir, M.Z., Mohd Ishak, Z.A., Mat Taib, R., Rahim, S.
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2013
Online Access:http://journalarticle.ukm.my/6076/
http://journalarticle.ukm.my/6076/1/02_M.Z._Ahmad_Thirmizir.pdf
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author Ahmad Thirmizir, M.Z.
Mohd Ishak, Z.A.
Mat Taib, R.
Rahim, S.
author_facet Ahmad Thirmizir, M.Z.
Mohd Ishak, Z.A.
Mat Taib, R.
Rahim, S.
author_sort Ahmad Thirmizir, M.Z.
building UKM Institutional Repository
collection Online Access
description Poly(butylene succinate) (PBS) composites with 30 wt.% loading of kenaf bast fibre (KBF) were compatibilised with 5 wt.% maleated PBS (PBS-g-MA). The maleic anhydride (MA) concentration in the compatibiliser was either 3, 5, 7 or 10 phr. In general, the compatibilised composites showed better flexural properties than the un-compatibilised composite. The highest increment in the flexural strength and modulus of 12.7 and 8.9%, respectively, were obtained with the addition of PBS-g-MA with MA concentration of 5 phr. Compatibilised and un-compatibilised PBS/KBF composites were immersed in distilled water for 90 days. The absorption of water by all the composites was observed to follow Fick’s law. The equilibrium moisture content, Mm, of the composites with PBS-g-MA at 3, 5 and 7 phr of MA concentrations was lower than that of the un-compatibilised composite due to improved fiber-matrix interfacial adhesion and reduction of voids content. Both un-compatibilised and compatibilised composites showed dimensional instability after the water absorption. This was probably due to the degradation of the fibre-matrix interfacial adhesion and fibre integrity. The flexural properties of these composites decreased after the water absorption. After re-drying only some of the flexural properties were recovered from plasticizing effect of water.
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spelling oai:generic.eprints.org:60762016-12-14T06:40:18Z http://journalarticle.ukm.my/6076/ Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites Ahmad Thirmizir, M.Z. Mohd Ishak, Z.A. Mat Taib, R. Rahim, S. Poly(butylene succinate) (PBS) composites with 30 wt.% loading of kenaf bast fibre (KBF) were compatibilised with 5 wt.% maleated PBS (PBS-g-MA). The maleic anhydride (MA) concentration in the compatibiliser was either 3, 5, 7 or 10 phr. In general, the compatibilised composites showed better flexural properties than the un-compatibilised composite. The highest increment in the flexural strength and modulus of 12.7 and 8.9%, respectively, were obtained with the addition of PBS-g-MA with MA concentration of 5 phr. Compatibilised and un-compatibilised PBS/KBF composites were immersed in distilled water for 90 days. The absorption of water by all the composites was observed to follow Fick’s law. The equilibrium moisture content, Mm, of the composites with PBS-g-MA at 3, 5 and 7 phr of MA concentrations was lower than that of the un-compatibilised composite due to improved fiber-matrix interfacial adhesion and reduction of voids content. Both un-compatibilised and compatibilised composites showed dimensional instability after the water absorption. This was probably due to the degradation of the fibre-matrix interfacial adhesion and fibre integrity. The flexural properties of these composites decreased after the water absorption. After re-drying only some of the flexural properties were recovered from plasticizing effect of water. Universiti Kebangsaan Malaysia 2013-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/6076/1/02_M.Z._Ahmad_Thirmizir.pdf Ahmad Thirmizir, M.Z. and Mohd Ishak, Z.A. and Mat Taib, R. and Rahim, S. (2013) Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites. Sains Malaysiana, 42 (4). pp. 435-441. ISSN 0126-6039 http://www.ukm.my/jsm/
spellingShingle Ahmad Thirmizir, M.Z.
Mohd Ishak, Z.A.
Mat Taib, R.
Rahim, S.
Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites
title Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites
title_full Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites
title_fullStr Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites
title_full_unstemmed Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites
title_short Effect of maleated compatibiliser (PBS-g-MA) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites
title_sort effect of maleated compatibiliser (pbs-g-ma) addition on the flexural properties and water absorption of poly(butylene succinate)/kenaf bast fibre composites
url http://journalarticle.ukm.my/6076/
http://journalarticle.ukm.my/6076/
http://journalarticle.ukm.my/6076/1/02_M.Z._Ahmad_Thirmizir.pdf