Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)
Two adducts of bis(N-benzyl-N-isopropyldithiocarbamato) zinc(II) with 2,2'-bipyridine and 1,10-phenanthroline have been successfully synthesized and characterized by elemental analysis and spectroscopic studies. The IR spectra of these adducts showed the thioureide band, v(C---- N) which occu...
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Universiti Kebangsaan Malaysia
2004
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| Online Access: | http://journalarticle.ukm.my/3885/ |
| _version_ | 1848810337943420928 |
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| author | Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz , Bohari M. Yamin, |
| author_facet | Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz , Bohari M. Yamin, |
| author_sort | Normah Awang, |
| building | UKM Institutional Repository |
| collection | Online Access |
| description | Two adducts of bis(N-benzyl-N-isopropyldithiocarbamato) zinc(II) with 2,2'-bipyridine and 1,10-phenanthroline have been successfully synthesized and characterized by elemental analysis and spectroscopic studies. The IR spectra of these adducts showed the thioureide band, v(C---- N) which occurred at 1440 and 1438 cm-1 respectively, lower than the parent compound at 1471 cm-1. The 13C NMR spectroscopic data for these compounds showed that the carbon signal from CS2 moiety shifted slightly downfield to 206.6 and 208.5 ppm compared to the parent compound at 205.1 ppm. The single crystal structure of bis (N-benzyl-N-isopropyldithiocarbamato )zinc(II)(bipy) has been determined. The structure of this compound showed monomeric nature with hexacoordination of the metal in a highly distorted octahedral geometry. |
| first_indexed | 2025-11-14T23:28:55Z |
| format | Article |
| id | oai:generic.eprints.org:3885 |
| institution | Universiti Kebangasaan Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T23:28:55Z |
| publishDate | 2004 |
| publisher | Universiti Kebangsaan Malaysia |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | oai:generic.eprints.org:38852012-03-23T01:10:07Z http://journalarticle.ukm.my/3885/ Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy) Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz , Bohari M. Yamin, Two adducts of bis(N-benzyl-N-isopropyldithiocarbamato) zinc(II) with 2,2'-bipyridine and 1,10-phenanthroline have been successfully synthesized and characterized by elemental analysis and spectroscopic studies. The IR spectra of these adducts showed the thioureide band, v(C---- N) which occurred at 1440 and 1438 cm-1 respectively, lower than the parent compound at 1471 cm-1. The 13C NMR spectroscopic data for these compounds showed that the carbon signal from CS2 moiety shifted slightly downfield to 206.6 and 208.5 ppm compared to the parent compound at 205.1 ppm. The single crystal structure of bis (N-benzyl-N-isopropyldithiocarbamato )zinc(II)(bipy) has been determined. The structure of this compound showed monomeric nature with hexacoordination of the metal in a highly distorted octahedral geometry. Universiti Kebangsaan Malaysia 2004 Article PeerReviewed Normah Awang, and Ibrahim Baba., and Y. Farina Abd. Aziz , and Bohari M. Yamin, (2004) Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy). Sains Malaysiana, 33 (2). pp. 45-53. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol33num2_2004/vol33num2_04page45-53.html |
| spellingShingle | Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz , Bohari M. Yamin, Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy) |
| title | Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy) |
| title_full | Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy) |
| title_fullStr | Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy) |
| title_full_unstemmed | Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy) |
| title_short | Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy) |
| title_sort | synthesis and characterization of bis(n-benzyl-nisopropyldithiocarbamato) zinc(ii) with bidentate nitrogen ligands: crystal structure of zn[s2cn (c7h7) (ic3h7)]2(bipy) |
| url | http://journalarticle.ukm.my/3885/ http://journalarticle.ukm.my/3885/ |