Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4

In-situ polymerization method was used to prepare palm-based polyurethane (PU) composites loading with 15 wt% magnetite (Fe3O4), polyaniline (PANI) and Fe3O4 coated with PANI labeled as PU15, PP and PPM, respectively. FTIR spectroscopy analysis indicated a shift in the carbonyl, C=O and NH in PP. Th...

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Main Authors: Liow, Chi Hao, Khairiah Hj Badri, Sahrim Hj. Ahmad
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2011
Online Access:http://journalarticle.ukm.my/2403/
http://journalarticle.ukm.my/2403/1/14_Liow.pdf
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author Liow, Chi Hao
Khairiah Hj Badri,
Sahrim Hj. Ahmad,
author_facet Liow, Chi Hao
Khairiah Hj Badri,
Sahrim Hj. Ahmad,
author_sort Liow, Chi Hao
building UKM Institutional Repository
collection Online Access
description In-situ polymerization method was used to prepare palm-based polyurethane (PU) composites loading with 15 wt% magnetite (Fe3O4), polyaniline (PANI) and Fe3O4 coated with PANI labeled as PU15, PP and PPM, respectively. FTIR spectroscopy analysis indicated a shift in the carbonyl, C=O and NH in PP. The shift of the peak indicated that there was hydrogen bonding between the C=O (proton acceptor) of urethane with NH (proton-donator) of PANI. PPM gave the highest impact and flexural strengths at 4875 kJ/ m2 and 42 MPa, respectively but with the lowest flexural modulus (1050 MPa). Two-stage degradation behavior was observed in the TGA thermogram.
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spelling oai:generic.eprints.org:24032016-12-14T06:31:30Z http://journalarticle.ukm.my/2403/ Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4 Liow, Chi Hao Khairiah Hj Badri, Sahrim Hj. Ahmad, In-situ polymerization method was used to prepare palm-based polyurethane (PU) composites loading with 15 wt% magnetite (Fe3O4), polyaniline (PANI) and Fe3O4 coated with PANI labeled as PU15, PP and PPM, respectively. FTIR spectroscopy analysis indicated a shift in the carbonyl, C=O and NH in PP. The shift of the peak indicated that there was hydrogen bonding between the C=O (proton acceptor) of urethane with NH (proton-donator) of PANI. PPM gave the highest impact and flexural strengths at 4875 kJ/ m2 and 42 MPa, respectively but with the lowest flexural modulus (1050 MPa). Two-stage degradation behavior was observed in the TGA thermogram. Universiti Kebangsaan Malaysia 2011-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/2403/1/14_Liow.pdf Liow, Chi Hao and Khairiah Hj Badri, and Sahrim Hj. Ahmad, (2011) Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4. Sains Malaysiana, 40 (4). pp. 373-378. ISSN 0126-6039 http://www.ukm.my/jsm/
spellingShingle Liow, Chi Hao
Khairiah Hj Badri,
Sahrim Hj. Ahmad,
Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4
title Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4
title_full Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4
title_fullStr Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4
title_full_unstemmed Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4
title_short Mechanical and thermal properties of palm-based polyurethane composites filled with Fe3O4, PANI and PANI/Fe3O4
title_sort mechanical and thermal properties of palm-based polyurethane composites filled with fe3o4, pani and pani/fe3o4
url http://journalarticle.ukm.my/2403/
http://journalarticle.ukm.my/2403/
http://journalarticle.ukm.my/2403/1/14_Liow.pdf