Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite

Iron (III) oxide (Fe2 O3 ) pillarized Na-montmorillonite (NaMMT) was prepared by ion-exchanging and calcining three different concentrations (0.025, 0.05, and 0.075 M) of Fe(OH)3 with NaMMT. The obtained materials were then examined for its ability to capture carbon dioxide, using thermogravimetric...

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Main Authors: Russamsi, Muhammad Nauval Farras, Nainggolan, Firman Joshua, Wungu, Triati Dewi Kencana, Suprijadi
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2024
Online Access:http://journalarticle.ukm.my/23652/
http://journalarticle.ukm.my/23652/1/SDD%2014.pdf
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author Russamsi, Muhammad Nauval Farras
Nainggolan, Firman Joshua
Wungu, Triati Dewi Kencana
Suprijadi,
author_facet Russamsi, Muhammad Nauval Farras
Nainggolan, Firman Joshua
Wungu, Triati Dewi Kencana
Suprijadi,
author_sort Russamsi, Muhammad Nauval Farras
building UKM Institutional Repository
collection Online Access
description Iron (III) oxide (Fe2 O3 ) pillarized Na-montmorillonite (NaMMT) was prepared by ion-exchanging and calcining three different concentrations (0.025, 0.05, and 0.075 M) of Fe(OH)3 with NaMMT. The obtained materials were then examined for its ability to capture carbon dioxide, using thermogravimetric methods. The structural, compositional, and textural changes caused by pillarization were also examined using XRD, XRF, FTIR, and BET-BJH. The results showed that NaMMT-0.025 (pillared using 0.025 M of Fe(OH)3 ) and NaMMT-0.075 exhibit superior adsorption capacity compared to NaMMT, with NaMMT-0.025 having the greatest capacity. By contrast, NaMMT-0.05 registers a decrease in the amount of CO2 adsorbed, compared to NaMMT. Using XRF, it was shown that the amount of Fe2 O3 present in the samples correspond to the concentration of Fe(OH)3 used in ion-exchange. XRD results shows that the interlayer space of NaMMT barely changed after addition of Fe2 O3 . Using FTIR, successful pillarization of Fe2 O3 is confirmed, and by combining it with BET-BJH, it shows that addition of Fe2 O3 could enhance carbon capture by creating favourable pore structures. Overall, it shows that adding an appropriate amount of Fe2 O3 to montmorillonite will enhance CO2 adsorption.
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spelling oai:generic.eprints.org:236522024-06-07T07:44:42Z http://journalarticle.ukm.my/23652/ Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite Russamsi, Muhammad Nauval Farras Nainggolan, Firman Joshua Wungu, Triati Dewi Kencana Suprijadi, Iron (III) oxide (Fe2 O3 ) pillarized Na-montmorillonite (NaMMT) was prepared by ion-exchanging and calcining three different concentrations (0.025, 0.05, and 0.075 M) of Fe(OH)3 with NaMMT. The obtained materials were then examined for its ability to capture carbon dioxide, using thermogravimetric methods. The structural, compositional, and textural changes caused by pillarization were also examined using XRD, XRF, FTIR, and BET-BJH. The results showed that NaMMT-0.025 (pillared using 0.025 M of Fe(OH)3 ) and NaMMT-0.075 exhibit superior adsorption capacity compared to NaMMT, with NaMMT-0.025 having the greatest capacity. By contrast, NaMMT-0.05 registers a decrease in the amount of CO2 adsorbed, compared to NaMMT. Using XRF, it was shown that the amount of Fe2 O3 present in the samples correspond to the concentration of Fe(OH)3 used in ion-exchange. XRD results shows that the interlayer space of NaMMT barely changed after addition of Fe2 O3 . Using FTIR, successful pillarization of Fe2 O3 is confirmed, and by combining it with BET-BJH, it shows that addition of Fe2 O3 could enhance carbon capture by creating favourable pore structures. Overall, it shows that adding an appropriate amount of Fe2 O3 to montmorillonite will enhance CO2 adsorption. Penerbit Universiti Kebangsaan Malaysia 2024 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/23652/1/SDD%2014.pdf Russamsi, Muhammad Nauval Farras and Nainggolan, Firman Joshua and Wungu, Triati Dewi Kencana and Suprijadi, (2024) Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite. Sains Malaysiana, 53 (2). pp. 409-419. ISSN 0126-6039 https://www.ukm.my/jsm/english_journals/vol53num2_2024/contentsVol53num2_2024.html
spellingShingle Russamsi, Muhammad Nauval Farras
Nainggolan, Firman Joshua
Wungu, Triati Dewi Kencana
Suprijadi,
Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite
title Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite
title_full Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite
title_fullStr Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite
title_full_unstemmed Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite
title_short Carbon dioxide adsorption on iron (III) oxide pillarized Na-montmorillonite
title_sort carbon dioxide adsorption on iron (iii) oxide pillarized na-montmorillonite
url http://journalarticle.ukm.my/23652/
http://journalarticle.ukm.my/23652/
http://journalarticle.ukm.my/23652/1/SDD%2014.pdf