A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes

Sappan wood (Caesalpinia sappan) is very well known as a natural dye for traditional food and beverage in many countries. Recently, there are many reports of sappan wood adulteration by adding synthetic or natural dyes to obtain quality color and better appearance. In this study, UV-Vis absorption s...

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Main Authors: Batubara, Irmanida, SaadatulHusna, Rafi, Mohamad, Sumaryada, Tony, Uchiyama, Susumu, Juliandi, Berry, Sastia Prama Putri, Fukusaki, Eiichiro
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2022
Online Access:http://journalarticle.ukm.my/19162/
http://journalarticle.ukm.my/19162/1/11.pdf
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author Batubara, Irmanida
SaadatulHusna,
Rafi, Mohamad
Sumaryada, Tony
Uchiyama, Susumu
Juliandi, Berry
Sastia Prama Putri,
Fukusaki, Eiichiro
author_facet Batubara, Irmanida
SaadatulHusna,
Rafi, Mohamad
Sumaryada, Tony
Uchiyama, Susumu
Juliandi, Berry
Sastia Prama Putri,
Fukusaki, Eiichiro
author_sort Batubara, Irmanida
building UKM Institutional Repository
collection Online Access
description Sappan wood (Caesalpinia sappan) is very well known as a natural dye for traditional food and beverage in many countries. Recently, there are many reports of sappan wood adulteration by adding synthetic or natural dyes to obtain quality color and better appearance. In this study, UV-Vis absorption spectra coupled with chemometrics were used to develop rapid detection of sappan wood raw material adulteration (authentication) from three dyes, i.e., sudan III, commercial textile dyes, and red yeast rice. Absorption spectra of 13 sappan wood raw material and adulterated sappan wood with the three dyes in two different concentrations which resulted about 78 adulterated samples were measured with UV-Vis spectrophotometer at a wavelength range of 200-800 nm. A principal component analysis followed by discriminant analysis was used to construct a model for the authentication of sappan wood from the three dyes used in this study. The combination of both methods was successfully classified sappan wood as non-adulterated and adulterated with the dyes. Cross-validation results of the authentication model of sappan wood from sudan III, commercial textile dyes, and red yeast rice were 94.12%, 94.12%, and 92.16% correctly classified into their groups, respectively.
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spelling oai:generic.eprints.org:191622022-08-01T04:14:05Z http://journalarticle.ukm.my/19162/ A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes Batubara, Irmanida SaadatulHusna, Rafi, Mohamad Sumaryada, Tony Uchiyama, Susumu Juliandi, Berry Sastia Prama Putri, Fukusaki, Eiichiro Sappan wood (Caesalpinia sappan) is very well known as a natural dye for traditional food and beverage in many countries. Recently, there are many reports of sappan wood adulteration by adding synthetic or natural dyes to obtain quality color and better appearance. In this study, UV-Vis absorption spectra coupled with chemometrics were used to develop rapid detection of sappan wood raw material adulteration (authentication) from three dyes, i.e., sudan III, commercial textile dyes, and red yeast rice. Absorption spectra of 13 sappan wood raw material and adulterated sappan wood with the three dyes in two different concentrations which resulted about 78 adulterated samples were measured with UV-Vis spectrophotometer at a wavelength range of 200-800 nm. A principal component analysis followed by discriminant analysis was used to construct a model for the authentication of sappan wood from the three dyes used in this study. The combination of both methods was successfully classified sappan wood as non-adulterated and adulterated with the dyes. Cross-validation results of the authentication model of sappan wood from sudan III, commercial textile dyes, and red yeast rice were 94.12%, 94.12%, and 92.16% correctly classified into their groups, respectively. Penerbit Universiti Kebangsaan Malaysia 2022-03 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/19162/1/11.pdf Batubara, Irmanida and SaadatulHusna, and Rafi, Mohamad and Sumaryada, Tony and Uchiyama, Susumu and Juliandi, Berry and Sastia Prama Putri, and Fukusaki, Eiichiro (2022) A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes. Sains Malaysiana, 51 (3). pp. 775-781. ISSN 0126-6039 https://www.ukm.my/jsm/malay_journals/jilid51bil3_2022/KandunganJilid51Bil3_2022.html
spellingShingle Batubara, Irmanida
SaadatulHusna,
Rafi, Mohamad
Sumaryada, Tony
Uchiyama, Susumu
Juliandi, Berry
Sastia Prama Putri,
Fukusaki, Eiichiro
A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes
title A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes
title_full A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes
title_fullStr A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes
title_full_unstemmed A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes
title_short A combination of UV-Vis spectroscopy and chemometrics for detection of sappanwood (Caesalpinia sappan) adulteration from three dyes
title_sort combination of uv-vis spectroscopy and chemometrics for detection of sappanwood (caesalpinia sappan) adulteration from three dyes
url http://journalarticle.ukm.my/19162/
http://journalarticle.ukm.my/19162/
http://journalarticle.ukm.my/19162/1/11.pdf