Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder
Adsorption capacity is one of the concern parameters in synthesizing an adsorbent for wastewater treatment. In this research, a bio-sorbent prepared by treating neem leaf powder with a chelating agent; carbon di-sulphide (CS2 ) through xanthation reaction was synthesized. The effect of treating w...
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| Format: | Article |
| Language: | English |
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Penerbit Universiti Kebangsaan Malaysia
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| Online Access: | http://journalarticle.ukm.my/15622/ http://journalarticle.ukm.my/15622/1/11.pdf |
| _version_ | 1848813843362349056 |
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| author | Mardhiah Ismail, Kamal Megat Hanafiah, |
| author_facet | Mardhiah Ismail, Kamal Megat Hanafiah, |
| author_sort | Mardhiah Ismail, |
| building | UKM Institutional Repository |
| collection | Online Access |
| description | Adsorption capacity is one of the concern parameters in synthesizing an adsorbent for wastewater treatment. In this
research, a bio-sorbent prepared by treating neem leaf powder with a chelating agent; carbon di-sulphide (CS2
)
through xanthation reaction was synthesized. The effect of treating with ligand (CS2
) will be investigate since ligand
will bind to metal ion. Ligand or chelating agent can help in increasing the ability of adsorbent to bind a metal ion in
an aqueous solution. The chemistry of adsorption of Pb(II) ion on xanthated neem leaf powder (XNL) was investigated
by using batch adsorption study. The maximum adsorption capacity, 256.41 mg g-1 at 318 K was determined from
isotherm study, obtained from Langmuir model. FTIR spectroscopy suggested that the adsorption of Pb(II) onto XNL
could possibly occur through ion exchange, Van der Wall forces and ionic interaction. |
| first_indexed | 2025-11-15T00:24:38Z |
| format | Article |
| id | oai:generic.eprints.org:15622 |
| institution | Universiti Kebangasaan Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T00:24:38Z |
| publisher | Penerbit Universiti Kebangsaan Malaysia |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | oai:generic.eprints.org:156222020-11-11T16:31:12Z http://journalarticle.ukm.my/15622/ Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder Mardhiah Ismail, Kamal Megat Hanafiah, Adsorption capacity is one of the concern parameters in synthesizing an adsorbent for wastewater treatment. In this research, a bio-sorbent prepared by treating neem leaf powder with a chelating agent; carbon di-sulphide (CS2 ) through xanthation reaction was synthesized. The effect of treating with ligand (CS2 ) will be investigate since ligand will bind to metal ion. Ligand or chelating agent can help in increasing the ability of adsorbent to bind a metal ion in an aqueous solution. The chemistry of adsorption of Pb(II) ion on xanthated neem leaf powder (XNL) was investigated by using batch adsorption study. The maximum adsorption capacity, 256.41 mg g-1 at 318 K was determined from isotherm study, obtained from Langmuir model. FTIR spectroscopy suggested that the adsorption of Pb(II) onto XNL could possibly occur through ion exchange, Van der Wall forces and ionic interaction. Penerbit Universiti Kebangsaan Malaysia Article PeerReviewed application/pdf en http://journalarticle.ukm.my/15622/1/11.pdf Mardhiah Ismail, and Kamal Megat Hanafiah, Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder. Sains Malaysiana, 49 (7). pp. 1585-1596. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid49bil7_2020/KandunganJilid49Bil7_2020.html |
| spellingShingle | Mardhiah Ismail, Kamal Megat Hanafiah, Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder |
| title | Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder |
| title_full | Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder |
| title_fullStr | Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder |
| title_full_unstemmed | Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder |
| title_short | Kinetic, isotherm, and possible mechanism of Pb(II) ion adsorption onto xanthated neem (Azadirachta indica) leaf powder |
| title_sort | kinetic, isotherm, and possible mechanism of pb(ii) ion adsorption onto xanthated neem (azadirachta indica) leaf powder |
| url | http://journalarticle.ukm.my/15622/ http://journalarticle.ukm.my/15622/ http://journalarticle.ukm.my/15622/1/11.pdf |