Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method
Praseodymium ion, Pr3+ doped Gd2O2S nanophosphors were successfully synthesized via gamma irradiation route along with the heat treatment. The effect of the gamma irradiation (0-150 kGy) on the structural, morphology and photoluminescence properties of Gd2O2S:Pr3+ were characterized via X-ray diffra...
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| Format: | Article |
| Language: | English |
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Penerbit Universiti Kebangsaan Malaysia
2018
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| Online Access: | http://journalarticle.ukm.my/12210/ http://journalarticle.ukm.my/12210/1/26%20Muhammad%20Hassyakirin%20Hasim.pdf |
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| author | Muhammad Hassyakirin Hasim, Irman Abdul Rahman, Sapizah Rahim, Muhammad Taqiyuddin Mawardi Ayob, Liyana Mohd Ali Napia, Shahidan Radiman, |
| author_facet | Muhammad Hassyakirin Hasim, Irman Abdul Rahman, Sapizah Rahim, Muhammad Taqiyuddin Mawardi Ayob, Liyana Mohd Ali Napia, Shahidan Radiman, |
| author_sort | Muhammad Hassyakirin Hasim, |
| building | UKM Institutional Repository |
| collection | Online Access |
| description | Praseodymium ion, Pr3+ doped Gd2O2S nanophosphors were successfully synthesized via gamma irradiation route along with the heat treatment. The effect of the gamma irradiation (0-150 kGy) on the structural, morphology and photoluminescence properties of Gd2O2S:Pr3+ were characterized via X-ray diffraction (XRD), field emission scanning electron microscope (FESEM) and photoluminescence spectroscopy (PL). The thermal properties of precursor sample were tested by the thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The chemical bonding of the precursor samples were analyzed by Fourier transform infrared spectroscopy (FT-IR). The XRD result confirmed the formation of hexagonal phase of Gd2O2S:Pr3+ without the presence of any impurities. The FESEM inspection showed the non-symmetrical shape of particles transformed into grain-like shape. The optimum photoluminescence (PL) emission intensities of Gd2-xO2S:xPr3+ occur at 50 kGy dose of gamma irradiation and 2 mol% concentration dopant of Pr3+ ions. The spectra under 325 nm UV excitation shows a strong green emission at 515 nm, which match the 3P0 → 3H4 transition of Pr3+ ions. The Gd2O2S:Pr3+ nanophosphors possessed many useful approaches in various applications mainly as radiation detection and biomedical diagnostic. |
| first_indexed | 2025-11-15T00:10:16Z |
| format | Article |
| id | oai:generic.eprints.org:12210 |
| institution | Universiti Kebangasaan Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T00:10:16Z |
| publishDate | 2018 |
| publisher | Penerbit Universiti Kebangsaan Malaysia |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | oai:generic.eprints.org:122102018-10-16T13:42:45Z http://journalarticle.ukm.my/12210/ Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method Muhammad Hassyakirin Hasim, Irman Abdul Rahman, Sapizah Rahim, Muhammad Taqiyuddin Mawardi Ayob, Liyana Mohd Ali Napia, Shahidan Radiman, Praseodymium ion, Pr3+ doped Gd2O2S nanophosphors were successfully synthesized via gamma irradiation route along with the heat treatment. The effect of the gamma irradiation (0-150 kGy) on the structural, morphology and photoluminescence properties of Gd2O2S:Pr3+ were characterized via X-ray diffraction (XRD), field emission scanning electron microscope (FESEM) and photoluminescence spectroscopy (PL). The thermal properties of precursor sample were tested by the thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The chemical bonding of the precursor samples were analyzed by Fourier transform infrared spectroscopy (FT-IR). The XRD result confirmed the formation of hexagonal phase of Gd2O2S:Pr3+ without the presence of any impurities. The FESEM inspection showed the non-symmetrical shape of particles transformed into grain-like shape. The optimum photoluminescence (PL) emission intensities of Gd2-xO2S:xPr3+ occur at 50 kGy dose of gamma irradiation and 2 mol% concentration dopant of Pr3+ ions. The spectra under 325 nm UV excitation shows a strong green emission at 515 nm, which match the 3P0 → 3H4 transition of Pr3+ ions. The Gd2O2S:Pr3+ nanophosphors possessed many useful approaches in various applications mainly as radiation detection and biomedical diagnostic. Penerbit Universiti Kebangsaan Malaysia 2018-08 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/12210/1/26%20Muhammad%20Hassyakirin%20Hasim.pdf Muhammad Hassyakirin Hasim, and Irman Abdul Rahman, and Sapizah Rahim, and Muhammad Taqiyuddin Mawardi Ayob, and Liyana Mohd Ali Napia, and Shahidan Radiman, (2018) Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method. Sains Malaysiana, 47 (8). pp. 1861-1866. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol47num8_2018/contentsVol47num8_2018.html |
| spellingShingle | Muhammad Hassyakirin Hasim, Irman Abdul Rahman, Sapizah Rahim, Muhammad Taqiyuddin Mawardi Ayob, Liyana Mohd Ali Napia, Shahidan Radiman, Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method |
| title | Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method |
| title_full | Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method |
| title_fullStr | Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method |
| title_full_unstemmed | Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method |
| title_short | Synthesis and characterization of Gd2O2S:Pr3+ nanophosphors using gamma irradiation method |
| title_sort | synthesis and characterization of gd2o2s:pr3+ nanophosphors using gamma irradiation method |
| url | http://journalarticle.ukm.my/12210/ http://journalarticle.ukm.my/12210/ http://journalarticle.ukm.my/12210/1/26%20Muhammad%20Hassyakirin%20Hasim.pdf |