Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions
C-4-phenacyloxy phenyl calix[4]resorcinarene (CPPCR) was synthesized by acidic condensation of 4-hydroxybenzaldehyde and resorcinol. The adsorption of CPPCR for Pb(II), Cd(II) and Cr(III) has been studied by measuring the metal concentration in aqueous solution using Atomic Absorption Spectrophotome...
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| Format: | Article |
| Language: | English |
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Penerbit Universiti Kebangsaan Malaysia
2018
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| Online Access: | http://journalarticle.ukm.my/12121/ http://journalarticle.ukm.my/12121/1/12%20Undri%20Rastuti.pdf |
| _version_ | 1848812914771755008 |
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| author | Rastuti, Undri Siswanta, Dwi Pambudi, Wisnu Nurohmah, Beta Achromi Bohari M. Yamin, Jumina, |
| author_facet | Rastuti, Undri Siswanta, Dwi Pambudi, Wisnu Nurohmah, Beta Achromi Bohari M. Yamin, Jumina, |
| author_sort | Rastuti, Undri |
| building | UKM Institutional Repository |
| collection | Online Access |
| description | C-4-phenacyloxy phenyl calix[4]resorcinarene (CPPCR) was synthesized by acidic condensation of 4-hydroxybenzaldehyde and resorcinol. The adsorption of CPPCR for Pb(II), Cd(II) and Cr(III) has been studied by measuring the metal concentration in aqueous solution using Atomic Absorption Spectrophotometry (AAS). The effects of solution pH, contact time and initial concentration of metal ions on the adsorption capacity of CPPCR were investigated. The adsorption kinetic of all the ions obeyed the Ho and McKay pseudo 2nd order rate law and the adsorption isotherm profile matched very well with Langmuir model. The separation factor (RL) of CPPCR for Pb(II), Cd(II) and Cr(III) were 0.190, 0.017, and 0.065, respectively, indicating the formation of monolayer behaviour. The Gibb free energy (ΔG) of the adsorption for all the metal ions have negative values indicating the adsorption process of Pb(II), Cd(II) and Cr(III) by CPPCR are spontaneous. |
| first_indexed | 2025-11-15T00:09:52Z |
| format | Article |
| id | oai:generic.eprints.org:12121 |
| institution | Universiti Kebangasaan Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T00:09:52Z |
| publishDate | 2018 |
| publisher | Penerbit Universiti Kebangsaan Malaysia |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | oai:generic.eprints.org:121212018-09-28T22:17:28Z http://journalarticle.ukm.my/12121/ Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions Rastuti, Undri Siswanta, Dwi Pambudi, Wisnu Nurohmah, Beta Achromi Bohari M. Yamin, Jumina, C-4-phenacyloxy phenyl calix[4]resorcinarene (CPPCR) was synthesized by acidic condensation of 4-hydroxybenzaldehyde and resorcinol. The adsorption of CPPCR for Pb(II), Cd(II) and Cr(III) has been studied by measuring the metal concentration in aqueous solution using Atomic Absorption Spectrophotometry (AAS). The effects of solution pH, contact time and initial concentration of metal ions on the adsorption capacity of CPPCR were investigated. The adsorption kinetic of all the ions obeyed the Ho and McKay pseudo 2nd order rate law and the adsorption isotherm profile matched very well with Langmuir model. The separation factor (RL) of CPPCR for Pb(II), Cd(II) and Cr(III) were 0.190, 0.017, and 0.065, respectively, indicating the formation of monolayer behaviour. The Gibb free energy (ΔG) of the adsorption for all the metal ions have negative values indicating the adsorption process of Pb(II), Cd(II) and Cr(III) by CPPCR are spontaneous. Penerbit Universiti Kebangsaan Malaysia 2018-06 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/12121/1/12%20Undri%20Rastuti.pdf Rastuti, Undri and Siswanta, Dwi and Pambudi, Wisnu and Nurohmah, Beta Achromi and Bohari M. Yamin, and Jumina, (2018) Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions. Sains Malaysiana, 47 (6). pp. 1167-1179. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid47bil6_2018/KandunganJilid47Bil6_2018.html |
| spellingShingle | Rastuti, Undri Siswanta, Dwi Pambudi, Wisnu Nurohmah, Beta Achromi Bohari M. Yamin, Jumina, Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions |
| title | Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions |
| title_full | Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions |
| title_fullStr | Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions |
| title_full_unstemmed | Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions |
| title_short | Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions |
| title_sort | synthesis, characterization and adsorption study of c-4-phenacyloxy-phenylcalix[4]resorcinarene for pb(ii), cd(ii) and cr(iii) ions |
| url | http://journalarticle.ukm.my/12121/ http://journalarticle.ukm.my/12121/ http://journalarticle.ukm.my/12121/1/12%20Undri%20Rastuti.pdf |