DNA charge neutralisation by linear polymers II: reversible binding

We model the way in which polymers bind to DNA and neutralise its charged backbone by analysing the dynamics of the distribution of gaps along the DNA. We generalise existing theory for irreversible binding to construct new deterministic models which include polymer removal, movement along the...

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Main Authors: Maltsev, Eugene, Wattis, Jonathan A.D., Byrne, Helen M.
Format: Article
Published: 2006
Online Access:https://eprints.nottingham.ac.uk/936/
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author Maltsev, Eugene
Wattis, Jonathan A.D.
Byrne, Helen M.
author_facet Maltsev, Eugene
Wattis, Jonathan A.D.
Byrne, Helen M.
author_sort Maltsev, Eugene
building Nottingham Research Data Repository
collection Online Access
description We model the way in which polymers bind to DNA and neutralise its charged backbone by analysing the dynamics of the distribution of gaps along the DNA. We generalise existing theory for irreversible binding to construct new deterministic models which include polymer removal, movement along the DNA and allow for binding with overlaps. We show that reversible binding alters the capacity of the DNA for polymers by allowing the rearrangement of polymer positions over a longer timescale than when binding is irreversible. When the polymers do not overlap, allowing reversible binding increases the number of polymers adhered and hence the charge that the DNA can accommodate; in contrast, when overlaps occur, reversible binding reduces the amount of charge neutralised by the polymers.
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spelling nottingham-9362020-05-04T20:30:07Z https://eprints.nottingham.ac.uk/936/ DNA charge neutralisation by linear polymers II: reversible binding Maltsev, Eugene Wattis, Jonathan A.D. Byrne, Helen M. We model the way in which polymers bind to DNA and neutralise its charged backbone by analysing the dynamics of the distribution of gaps along the DNA. We generalise existing theory for irreversible binding to construct new deterministic models which include polymer removal, movement along the DNA and allow for binding with overlaps. We show that reversible binding alters the capacity of the DNA for polymers by allowing the rearrangement of polymer positions over a longer timescale than when binding is irreversible. When the polymers do not overlap, allowing reversible binding increases the number of polymers adhered and hence the charge that the DNA can accommodate; in contrast, when overlaps occur, reversible binding reduces the amount of charge neutralised by the polymers. 2006 Article PeerReviewed Maltsev, Eugene, Wattis, Jonathan A.D. and Byrne, Helen M. (2006) DNA charge neutralisation by linear polymers II: reversible binding. Physical Review E, 74 . 041918. ISSN 1539-3755 http://pre.aps.org/browse
spellingShingle Maltsev, Eugene
Wattis, Jonathan A.D.
Byrne, Helen M.
DNA charge neutralisation by linear polymers II: reversible binding
title DNA charge neutralisation by linear polymers II: reversible binding
title_full DNA charge neutralisation by linear polymers II: reversible binding
title_fullStr DNA charge neutralisation by linear polymers II: reversible binding
title_full_unstemmed DNA charge neutralisation by linear polymers II: reversible binding
title_short DNA charge neutralisation by linear polymers II: reversible binding
title_sort dna charge neutralisation by linear polymers ii: reversible binding
url https://eprints.nottingham.ac.uk/936/
https://eprints.nottingham.ac.uk/936/