Caged Compounds: A Novel Synthesis of Homocubane and its Analogues and Gold-(I) Catalysed Propargylation of Azinium Salts

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Caged Compounds: A Novel Synthesis of Homocubane and its Analogues and Gold-(I) Catalysed Propargylation of Azinium Salts

We disclose a novel synthetic method to access the homocubane ester 4a in 4 steps, in an overall yield comparable or superior to literature methods. The sequential transformations of a [6+2] cycloaddition, 4π electrocyclisation, followed by a dehydrogenation and [2+2] cycloaddition displays the rela...

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Bibliographic Details
Main Author:	Smithson, Jack
Format:	Thesis (University of Nottingham only)
Language:	English
Published:	2025
Subjects:	propargylation caged compounds catalysis DFT studies gold mechanism
Online Access:	https://eprints.nottingham.ac.uk/81034/

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