Design and Development of Organic Electrocatalysts for CO2 Reduction

The electrochemical carbon dioxide reduction reaction (CO2RR) represents a promising method for converting carbon waste streams into valuable chemicals. Current CO2RR electrocatalysts often rely on expensive and rare platinum group metals, highlighting the need for more sustainable and cost-effectiv...

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Main Author: Altemani, Fatin
Format: Thesis (University of Nottingham only)
Language:English
Published: 2025
Subjects:
Online Access:https://eprints.nottingham.ac.uk/80816/
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author Altemani, Fatin
author_facet Altemani, Fatin
author_sort Altemani, Fatin
building Nottingham Research Data Repository
collection Online Access
description The electrochemical carbon dioxide reduction reaction (CO2RR) represents a promising method for converting carbon waste streams into valuable chemicals. Current CO2RR electrocatalysts often rely on expensive and rare platinum group metals, highlighting the need for more sustainable and cost-effective alternatives. This thesis explores the use of aromatic nitro group-bearing catalysts for the CO2RR, focusing on their performance in different electrolyte systems. Cyclic voltammetry was employed to evaluate catalytic efficiency. Additionally, the influence of the electrolyte and gas environment (N2 vs. CO2) on the catalytic activity was investigated. Results demonstrated that aromatic nitro group catalysts exhibited improved CO2 reduction activity in both electrolyte systems. This study provides insights into the relationship between catalyst structure, electrolyte composition, and gas environment, suggesting that further optimization of these catalyst-electrolyte systems could enhance the efficiency and selectivity of the CO2RR, advancing sustainable chemical production processes.
first_indexed 2025-11-14T21:04:52Z
format Thesis (University of Nottingham only)
id nottingham-80816
institution University of Nottingham Malaysia Campus
institution_category Local University
language English
last_indexed 2025-11-14T21:04:52Z
publishDate 2025
recordtype eprints
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spelling nottingham-808162025-07-30T04:40:13Z https://eprints.nottingham.ac.uk/80816/ Design and Development of Organic Electrocatalysts for CO2 Reduction Altemani, Fatin The electrochemical carbon dioxide reduction reaction (CO2RR) represents a promising method for converting carbon waste streams into valuable chemicals. Current CO2RR electrocatalysts often rely on expensive and rare platinum group metals, highlighting the need for more sustainable and cost-effective alternatives. This thesis explores the use of aromatic nitro group-bearing catalysts for the CO2RR, focusing on their performance in different electrolyte systems. Cyclic voltammetry was employed to evaluate catalytic efficiency. Additionally, the influence of the electrolyte and gas environment (N2 vs. CO2) on the catalytic activity was investigated. Results demonstrated that aromatic nitro group catalysts exhibited improved CO2 reduction activity in both electrolyte systems. This study provides insights into the relationship between catalyst structure, electrolyte composition, and gas environment, suggesting that further optimization of these catalyst-electrolyte systems could enhance the efficiency and selectivity of the CO2RR, advancing sustainable chemical production processes. 2025-07-30 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en cc_by https://eprints.nottingham.ac.uk/80816/1/Thesis%20Final_Altemani_Fatin.pdf Altemani, Fatin (2025) Design and Development of Organic Electrocatalysts for CO2 Reduction. MRes thesis, University of Nottingham. Electrocatalysts carbon dioxide reduction reaction (CO2RR) nitro group catalysts cyclic voltammetry
spellingShingle Electrocatalysts
carbon dioxide reduction reaction (CO2RR)
nitro group catalysts
cyclic voltammetry
Altemani, Fatin
Design and Development of Organic Electrocatalysts for CO2 Reduction
title Design and Development of Organic Electrocatalysts for CO2 Reduction
title_full Design and Development of Organic Electrocatalysts for CO2 Reduction
title_fullStr Design and Development of Organic Electrocatalysts for CO2 Reduction
title_full_unstemmed Design and Development of Organic Electrocatalysts for CO2 Reduction
title_short Design and Development of Organic Electrocatalysts for CO2 Reduction
title_sort design and development of organic electrocatalysts for co2 reduction
topic Electrocatalysts
carbon dioxide reduction reaction (CO2RR)
nitro group catalysts
cyclic voltammetry
url https://eprints.nottingham.ac.uk/80816/