Synthesis and Complexation of a Bulky Silyl Phosphanide and Extended PNNNP Carbazole-based Ligand

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Synthesis and Complexation of a Bulky Silyl Phosphanide and Extended PNNNP Carbazole-based Ligand

In this work, the synthesis of the bulky phosphanide, [(iPr3Si)2P−] was investigated and optimised, leading to the isolation of the sodium phosphanide X2.14. This ligand was explored in preliminary coordinations with Co2+, Fe2+ and Zn2+ resulting in dimeric (X2.21, Co2+) and monomeric (X2.22, Fe2+ a...

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Bibliographic Details
Main Author:	Churchill, Olivia
Format:	Thesis (University of Nottingham only)
Language:	English
Published:	2024
Subjects:	phosphanide ligands synthesis
Online Access:	https://eprints.nottingham.ac.uk/77946/

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