INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS
In this thesis, three different supramolecular frameworks will be described. The first is a novel naphthalene diimide (NDI) metal-organic framework-based, flexible, nanotube structure. The crystal structure is reported and described. The structure was spectroscopically probed to investigate the fo...
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| Format: | Thesis (University of Nottingham only) |
| Language: | English |
| Published: |
2023
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| Online Access: | https://eprints.nottingham.ac.uk/76710/ |
| _version_ | 1848800930062925824 |
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| author | Newman, M. R. |
| author_facet | Newman, M. R. |
| author_sort | Newman, M. R. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | In this thesis, three different supramolecular frameworks will be described.
The first is a novel naphthalene diimide (NDI) metal-organic framework-based, flexible, nanotube structure. The crystal structure is reported and described. The structure was spectroscopically probed to investigate the formation of an NDI radical upon exposure to UV/Visible radiation and investigated by Raman spectroscopy to measure chemical changes upon mechanical bending of the nanotubes.
In the second section, two tetra-acid rotaxanes, TAR4 and TAR8 are synthesised and analysed by proton NMR and the single X-ray crystal of the former, is detailed. Once synthesised, attempts were made to incorporate these into metal-organic frameworks motifs through several methods. Two other diacid rotaxane syntheses were also started and the preliminary reactions to form them detailed.
The final chapter details the synthesis of a naphthalene diimide/porphyrin [2]handcuff rotaxane; which was planned and started, with these discussed. |
| first_indexed | 2025-11-14T20:59:23Z |
| format | Thesis (University of Nottingham only) |
| id | nottingham-76710 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T20:59:23Z |
| publishDate | 2023 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-767102024-03-20T15:33:21Z https://eprints.nottingham.ac.uk/76710/ INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS Newman, M. R. In this thesis, three different supramolecular frameworks will be described. The first is a novel naphthalene diimide (NDI) metal-organic framework-based, flexible, nanotube structure. The crystal structure is reported and described. The structure was spectroscopically probed to investigate the formation of an NDI radical upon exposure to UV/Visible radiation and investigated by Raman spectroscopy to measure chemical changes upon mechanical bending of the nanotubes. In the second section, two tetra-acid rotaxanes, TAR4 and TAR8 are synthesised and analysed by proton NMR and the single X-ray crystal of the former, is detailed. Once synthesised, attempts were made to incorporate these into metal-organic frameworks motifs through several methods. Two other diacid rotaxane syntheses were also started and the preliminary reactions to form them detailed. The final chapter details the synthesis of a naphthalene diimide/porphyrin [2]handcuff rotaxane; which was planned and started, with these discussed. 2023-12-12 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en cc_by https://eprints.nottingham.ac.uk/76710/1/Thesis%20Master%20-%20Corrected.pdf Newman, M. R. (2023) INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS. PhD thesis, University of Nottingham. supramolecular frameworks supramolecular chemistry organometallic compounds |
| spellingShingle | supramolecular frameworks supramolecular chemistry organometallic compounds Newman, M. R. INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS |
| title | INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS |
| title_full | INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS |
| title_fullStr | INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS |
| title_full_unstemmed | INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS |
| title_short | INCORPORATION OF COMPLEX MOLECULES AND SUPRAMOLECULAR STRUCTURES INTO METAL-ORGANIC FRAMEWORKS |
| title_sort | incorporation of complex molecules and supramolecular structures into metal-organic frameworks |
| topic | supramolecular frameworks supramolecular chemistry organometallic compounds |
| url | https://eprints.nottingham.ac.uk/76710/ |