Molecular simulation of protein-ligand complexes

Computational methods provide important contributions to modern drug discovery projects. In this thesis, we discuss the insights into protein-ligand interactions afforded by methods such as molecular docking, molecular dynamics (MD) and alchemical free energy calculations, which expedite the process...

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Main Author: Guest, Ellen
Format: Thesis (University of Nottingham only)
Language:English
Published: 2022
Subjects:
Online Access:https://eprints.nottingham.ac.uk/68947/
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author Guest, Ellen
author_facet Guest, Ellen
author_sort Guest, Ellen
building Nottingham Research Data Repository
collection Online Access
description Computational methods provide important contributions to modern drug discovery projects. In this thesis, we discuss the insights into protein-ligand interactions afforded by methods such as molecular docking, molecular dynamics (MD) and alchemical free energy calculations, which expedite the process of lead compound design and optimisation. These methods are applied to two case studies of biomolecular systems of therapeutic interest. The targets of the studies are the integrin αvβ6 and the bromodomain-containing protein 4 (BRD4). As the accuracy of molecular mechanics based methods relies on the quality of the force field in which the potential energy is calculated from, we focus on developing force field parameters for a series of small molecule inhibitors of αvβ6. Parameters are then applied to MD and relative free energy perturbation (FEP) simulations. MD simulations highlight the importance of hydrogen bonds, metal chelate interactions and cation-
first_indexed 2025-11-14T20:52:50Z
format Thesis (University of Nottingham only)
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institution University of Nottingham Malaysia Campus
institution_category Local University
language English
last_indexed 2025-11-14T20:52:50Z
publishDate 2022
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spelling nottingham-689472022-08-02T04:40:23Z https://eprints.nottingham.ac.uk/68947/ Molecular simulation of protein-ligand complexes Guest, Ellen Computational methods provide important contributions to modern drug discovery projects. In this thesis, we discuss the insights into protein-ligand interactions afforded by methods such as molecular docking, molecular dynamics (MD) and alchemical free energy calculations, which expedite the process of lead compound design and optimisation. These methods are applied to two case studies of biomolecular systems of therapeutic interest. The targets of the studies are the integrin αvβ6 and the bromodomain-containing protein 4 (BRD4). As the accuracy of molecular mechanics based methods relies on the quality of the force field in which the potential energy is calculated from, we focus on developing force field parameters for a series of small molecule inhibitors of αvβ6. Parameters are then applied to MD and relative free energy perturbation (FEP) simulations. MD simulations highlight the importance of hydrogen bonds, metal chelate interactions and cation- 2022-08-02 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en cc_by https://eprints.nottingham.ac.uk/68947/1/thesis_corrected.pdf Guest, Ellen (2022) Molecular simulation of protein-ligand complexes. PhD thesis, University of Nottingham. Protein-ligand complexes Molecular simulation
spellingShingle Protein-ligand complexes
Molecular simulation
Guest, Ellen
Molecular simulation of protein-ligand complexes
title Molecular simulation of protein-ligand complexes
title_full Molecular simulation of protein-ligand complexes
title_fullStr Molecular simulation of protein-ligand complexes
title_full_unstemmed Molecular simulation of protein-ligand complexes
title_short Molecular simulation of protein-ligand complexes
title_sort molecular simulation of protein-ligand complexes
topic Protein-ligand complexes
Molecular simulation
url https://eprints.nottingham.ac.uk/68947/