Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe)

This thesis presents an investigation of the optoelectronic properties of the two-dimensional (2D) van der Waals (vdW) semiconductor indium selenide (InSe) and exploits these properties in InSe-graphene vdW heterostructure devices. These heterostructures are fabricated by mechanical exfoliation and...

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Main Author: Mazumder, Debarati
Format: Thesis (University of Nottingham only)
Language:English
Published: 2022
Subjects:
Online Access:https://eprints.nottingham.ac.uk/68556/
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author Mazumder, Debarati
author_facet Mazumder, Debarati
author_sort Mazumder, Debarati
building Nottingham Research Data Repository
collection Online Access
description This thesis presents an investigation of the optoelectronic properties of the two-dimensional (2D) van der Waals (vdW) semiconductor indium selenide (InSe) and exploits these properties in InSe-graphene vdW heterostructure devices. These heterostructures are fabricated by mechanical exfoliation and dry transfer of InSe and graphene nanosheets. A novel method of device fabrication by needle transfer of graphene microsheets is also described and used for some devices. The optical properties of InSe nanosheets differ qualitatively from those reported for other 2D materials, such as transition metal dichalcogenides (TMDCs). In particular, this thesis reports on the controlled modulation of optical signals by exploiting the inherent optical anisotropy and mechanical flexibility of atomically thin 2D vdW InSe bent onto a periodic array of silicon (Si) nanopillars. A series of vertical and planar vdW heterostructures, including tunnelling transistors and photodetectors, are investigated. The optoelectronic transport characteristics of these devices exploit a favourable band alignment between InSe and graphene. Moreover, 2D energy subbands of InSe exhibit strong quantum confinement, offering a route to the modulation of electrical properties. Optical absorption studies on bulk InSe by variable angle spectroscopic ellipsometry (VASE) are presented, which indicates strong resonances in the ultra-violet (UV) range of the absorption spectrum. A fast, ultra-high photoresponsivity is demonstrated in a hybrid phototransistor based on an InSe/graphene heterostructure that exploits the light-induced charge transfer at the interface of InSe and graphene.
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format Thesis (University of Nottingham only)
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spelling nottingham-685562022-08-02T04:40:14Z https://eprints.nottingham.ac.uk/68556/ Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe) Mazumder, Debarati This thesis presents an investigation of the optoelectronic properties of the two-dimensional (2D) van der Waals (vdW) semiconductor indium selenide (InSe) and exploits these properties in InSe-graphene vdW heterostructure devices. These heterostructures are fabricated by mechanical exfoliation and dry transfer of InSe and graphene nanosheets. A novel method of device fabrication by needle transfer of graphene microsheets is also described and used for some devices. The optical properties of InSe nanosheets differ qualitatively from those reported for other 2D materials, such as transition metal dichalcogenides (TMDCs). In particular, this thesis reports on the controlled modulation of optical signals by exploiting the inherent optical anisotropy and mechanical flexibility of atomically thin 2D vdW InSe bent onto a periodic array of silicon (Si) nanopillars. A series of vertical and planar vdW heterostructures, including tunnelling transistors and photodetectors, are investigated. The optoelectronic transport characteristics of these devices exploit a favourable band alignment between InSe and graphene. Moreover, 2D energy subbands of InSe exhibit strong quantum confinement, offering a route to the modulation of electrical properties. Optical absorption studies on bulk InSe by variable angle spectroscopic ellipsometry (VASE) are presented, which indicates strong resonances in the ultra-violet (UV) range of the absorption spectrum. A fast, ultra-high photoresponsivity is demonstrated in a hybrid phototransistor based on an InSe/graphene heterostructure that exploits the light-induced charge transfer at the interface of InSe and graphene. 2022-08-02 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en cc_by https://eprints.nottingham.ac.uk/68556/1/Corrected%20Thesis_FEB28f.pdf Mazumder, Debarati (2022) Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe). PhD thesis, University of Nottingham. Optoelectronic Van der Waals semiconductor vdW Indium selenide InSe
spellingShingle Optoelectronic
Van der Waals semiconductor
vdW
Indium selenide
InSe
Mazumder, Debarati
Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe)
title Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe)
title_full Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe)
title_fullStr Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe)
title_full_unstemmed Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe)
title_short Optoelectronic properties of the two-dimensional van der Waals semiconductor indium selenide (InSe)
title_sort optoelectronic properties of the two-dimensional van der waals semiconductor indium selenide (inse)
topic Optoelectronic
Van der Waals semiconductor
vdW
Indium selenide
InSe
url https://eprints.nottingham.ac.uk/68556/